1-(4'-cyanobenzyl)-4-pyridinium bis(maleonitriledithiolate)nickelate(III) | 863774-43-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4'-cyanobenzyl)-4-pyridinium bis(maleonitriledithiolate)nickelate(III)
• CAS: 863774-43-0
• 化学式: C₈N₄NiS₄*C₁₃H₁₂N₃
• 分子量: 549.327
• InChiKey: AUIUMUXYHKMTSH-QDMRRLORSA-K

反应信息

• 作为产物：
  描述：

  bis(1-(4'-cyanobenzyl)-4-pyridinium) bis(maleonitriledithiolate)nickelate(II) 在 I₂ 作用下， 以 not given 为溶剂， 生成 1-(4'-cyanobenzyl)-4-pyridinium bis(maleonitriledithiolate)nickelate(III)
  参考文献：
  名称：

  Unusual magnetic transition around 210 K in a new 1D molecular solid based on ion

  摘要：

  A new ion-pair complex, [CNBzPyNH(2)][Ni(mnt)(2)] (1), where [CNBzPyNH(2)](+) = 1-(4'-cyanobenzyl)-4-aminopyridinium and mnt(2-) = maleonitriledithiolate, forms a completely segregated uniform stacking column with the Ni... Ni distance 3.863 Angstrom and shows a peculiar magnetic transition from paramagnetism in the high-temperature (HT) phase to spin gap in low-temperature (LT) phase around 210 K. The DSC analysis reveals that the phase transition is first order. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.11.024