N,N’-bis(pyridylcarbonyl)-4,4’-diaminodiphenyl ether | 328010-11-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N’-bis(pyridylcarbonyl)-4,4’-diaminodiphenyl ether
• 英文别名: N,N'-(Oxybis(4,1-phenylene))diisonicotinamide；N-[4-[4-(pyridine-4-carbonylamino)phenoxy]phenyl]pyridine-4-carboxamide
• CAS: 328010-11-3
• 化学式: C₂₄H₁₈N₄O₃
• mdl: MFCD00331403
• 分子量: 410.432
• InChiKey: BTXHEZCTEOYMPJ-UHFFFAOYSA-N

物化性质

• 熔点：
  273-276 °C (decomp)
• 沸点：
  488.4±40.0 °C(Predicted)
• 密度：
  1.349±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93.2
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N,N’-bis(pyridylcarbonyl)-4,4’-diaminodiphenyl ether 以 甲醇 、 氯仿 为溶剂， 生成 [Co(NO3)2(N,N'-bis(pyridylcarbonyl)-4,4'-diaminodiphenyl ether)2]*H2O
  参考文献：
  名称：

  A three-dimensional interpenetrating framework with spacious multi-channels: synthesis and characterisation of a cobalt(II) coordination polymer based on an angular dipyridyl ligand incorporating an amide spacer

  摘要：

  Self-assembly of Co(NO3)(2) and N, N'-bis(4-pyridylcarbonyl)-4,4'-diaminodiphenyl ether (L), a dipyridyl-based ligand separated by phenyl amide spacer, afforded an interpenetrating Co(II) coordination polymer {[CoL2(NO3)(2)] (.) 2(C2H5)(2)O (.) (CH3)(2)SO (.) H2O}(n) (1). X-ray analysis of 1 shows that a unique combination of coordination and hydrogen bonds within a framework gives this material a spacious multi-channel structure. Moreover, the crystalline framework of 1 is virtually unchanged after removing the solvent molecules from the channels resulting in a nanoporous structure with estimated free volume of 31.4%. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.12.018

文献信息

• Zn^II-Dipyridylamide-Based Coordination Frameworks: Structural Transformation and Anion Effect
  作者：Biing-Chiau Tzeng、Chien-Ting Yeh、Tsung-Yi Chang

  DOI：10.1002/cplu.201300332

  日期：2014.3

  Although the 1 D double-zigzag and 2 D polyrotaxane frameworks of ZnII -paps and -papo with ClO4 - anions can be also interconverted through heating and grinding in the presence of moisture, the related ZnII -papc framework with ClO4 - can only undergo a structural transformation process through heating. Surprisingly, reversible structural transformation between 5 and 6 has been proven successfully. In

  我们合成了一系列的一维双锯齿形（[Zn（papo）2（H2 O）2]（PF6）2} n（1），[Zn（papo）2（H2 O）2]（PF6 ）2} n（3）和[Zn（papc）2（H2 O）2]（PF6）2} n（5））和2 D聚轮烷（[Zn（papc）2（PF6）2] n（ 6））通过Zn（PF6）2与二吡啶酰胺配体（N，N'-双（吡啶基羰基）-4,4'-二氨基二苯基硫醚（PAP），N，N'-双（吡啶基羰基）-4，分别通过X射线衍射研究确定了4'-二氨基二苯醚（papo）和N，N'-（亚甲基二-对亚苯基）双吡啶-4-羧酰胺（papc），并确定了它们的分子结构。根据粉末X射线衍射（PXRD）实验，发现加热后，双锯齿形骨架1和3经过结构转化，得到各自的聚轮烷骨架2（[Zn（papo）2（PF6）2] n）和4（[Zn（papo）2（PF6）2] n），与他们的Zn（ClO4）2类似物非
• Structural Transformation of Zn^II-Dipyridylamide-Based Coordination Frameworks: Hybrid-Ligand and Metal Effects
  作者：Biing-Chiau Tzeng、Tsung-Yi Chang、Miao-Hsin Tsai、Yu-Ting Lin、Shiu-Feng Lee、Hwo-Shuenn Sheu

  DOI：10.1002/cplu.201402453

  日期：2015.5

  double-zigzag frameworks of 1, 3, 5, and 7 undergo structural transformation to give the respective polyrotaxane frameworks of 2, 4, 6, and 8. Moreover, grinding the solid samples of 2, 4, 6, and 8 in the presence of moisture also result in the total conversion back into the double-zigzag frameworks of 1, 3, 5, and 7, respectively. Remarkably, grinding the solid samples of polyrotaxane frameworks of 9 and

  通过Cu（ClO4）2与相应的二吡啶基酰胺配体的反应进行[Cu（papx）2（ ）2] n（x = s 9，o 10和c 11）的二维聚轮烷骨架的合成和结构表征出去。根据PXRD实验，加热后，1、3、5和7的双锯齿形骨架发生结构转变，分别得到2、4、6、6和8的聚轮烷骨架。此外，将2的固体样品研磨，4、6和8在存在水分的情况下也分别导致总转化成1、3、5和7的双曲折框架。值得注意的是，在水分存在下研磨9和10的聚轮烷骨架的固体样品无法诱导结构转变过程。c 11）通过Cu（ClO 4）2与相应的二吡啶酰胺配体的反应进行。根据PXRD实验，加热后，1、3、5和7的双锯齿形骨架发生结构转变，分别得到2、4、6、6和8的聚轮烷骨架。此外，将2的固体样品研磨，4、6和8在存在水分的情况下也分别导致总转化成1、3、5和7的双曲折框架。值得注意的是，在水分存在下研磨9和10的聚轮烷骨架的固体样品无法诱导结构转变过程。c
• M(II)-dipyridylamide-based coordination frameworks (M=Mn, Co, Ni): Structural transformation
  作者：Biing-Chiau Tzeng、TamilSelvi Selvam、Miao-Hsin Tsai

  DOI：10.1016/j.jssc.2016.08.011

  日期：2016.11

  Abstract A series of 1-D double-zigzag ([M(papx)2(H2O)2](ClO4)2}n; M=Mn, x=s (1), x=o (3); M=Co, x=s (4), x=o (5); M=Ni, x=s (6), x=o (7)) and 2-D polyrotaxane ([Mn(paps)2(ClO4)2]n (2)) frameworks were synthesized by reactions of M(ClO4)2 (M=Mn, Co, and Ni) with papx (paps, N,N’-bis(pyridylcarbonyl)-4,4’-diaminodiphenylthioether; papo, N,N’-bis(pyridylcarbonyl)-4,4’-diaminodiphenyl ether), which have

  摘要 一系列一维双曲折([M(papx)2(H2O)2](ClO4)2}n; M=Mn, x=s (1), x=o (3); M= Co, x=s (4), x=o (5); M=Ni, x=s (6), x=o (7)) 和二维聚轮烷 ([Mn(paps)2( )2 ]n (2)) 骨架是通过 M( )2（M=Mn、Co 和 Ni）与 papx（paps, N,N'-bis(pyridylcarbonyl)-4,4'-diaminodiphenylthioether; papo , N,N'-双(吡啶基羰基)-4,4'-二氨基二苯醚)，它们已被分离并通过 X 射线衍射对其结构进行了表征。基于粉末 X 射线衍射 (PXRD) 实验，加热双锯齿形框架进行结构转变，得到各自的聚轮烷。此外，在存在水分的情况下研磨各个聚轮烷的固体样品也导致完全转化为原始的双锯齿形框架。在这项研究中，
• Rational Design and Synthesis of Fe-Doped Co-Based Coordination Polymer Composite Photocatalysts for the Degradation of Norfloxacin and Ciprofloxacin
  作者：Ye-Xia Li、Xin Chen、Zhi-Yang Jiang、Jian Luan、Fang Guo

  DOI：10.1021/acs.inorgchem.4c00394

  日期：2024.4.8

  light-responsive Fe-doped Co-based coordination polymer (Fe@Co-CP) photocatalyst was synthesized under mild conditions. [Co(4-padpe)(1,3-BDC)]n (Co-CP) was first constructed using mixed ligands through the hydrothermal method. Then, Fe was introduced into the Co-CP framework to achieve the enhanced photocatalytic activity. The optimal Fe@Co-CP-2 exhibited excellent catalytic degradation performance for

  在温和条件下合成了太阳光响应型铁掺杂钴基配位聚合物（Fe@Co-CP）光催化剂。首先通过水热法使用混合配体构建[Co(4-padpe)(1,3-BDC)] n (Co-CP)。然后，将Fe引入到Co-CP骨架中以实现增强的光催化活性。最优的Fe@Co-CP-2在没有辅助氧化剂的阳光照射下对诺氟沙星和环丙沙星表现出优异的催化降解性能，120 min内降解率分别为91.25%和92.66%。这些优异的光催化性能归因于Fe-O键的生成，它不仅增强了光吸收强度，而且加速了电子和空穴的分离效率，从而显着提高了复合材料的光催化性能。同时，Fe@Co-CP-2表现出优异的稳定性和可重复使用性。此外，还有效分析了抗生素分子的降解途径和中间体。自由基清除实验和ESR结果证实， • OH、 • O 2 -和h +活性物种参与了催化降解反应。并深入研究了相应的机制。这项研究为构建铁掺杂Co-CP基复合材料作为降
• One-dimensional nanoporous M2L2 rhombohedral molecular square with strong blue fluorescent emission
  作者：Yong-Xiu Li、Yong-Hua Li、Xi-Rui Zeng、Ren-Gen Xiong、Xiao-Zeng You、Hoong-Kun Fun

  DOI：10.1016/s1387-7003(03)00181-3

  日期：2003.8

  The hydrothermal reactions of Zn(ClO4)(2).6H(2)O and Cd(ClO4)(2) . 6H(2)O with the ligand N,N'-bis(pyridylcarbonyl)-4,4'-diaminodiphenyl ether (L) afford two one-dimensional (1D) coordination polymers, ([CdL(ClO4)(2).(H2O)(2)].2H(2)O) (1) and [ZnL(ClO4)(2) . (H2O)(2)].2H(2)O, (2) having a nanoporous M2L2 rhombohedral molecular square with an approximately accessible cavity of 12.9 x 12.9 (1) and 12.7 x 12.7 (2) Angstrom without any interpenetrations. Both 1 and 2 are isostructural and display very strong blue fluorescent emission in the solid state at room temperature. (C) 2003 Elsevier Science B.V. All rights reserved.