| 261911-06-2

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 261911-06-2
• 化学式: C₂₅H₂₇MnN₅O₆
• 分子量: 548.457
• InChiKey: YQSMLYSOMUWBSI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙醇 、 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  结晶溶剂对 MnII 和 NiII 与 2,6-双(1-水杨酰肼基乙基)吡啶、H4daps 配合物晶体结构的影响

  摘要：

  Neutral manganese and nickel complexes of the empirical formulae Mn(H(2)daps)(H2O)(0.5) and Ni(H(2)daps) (H2O)(1.5)(CH3CN) have been prepared by electrochemical syntheses. The structures of the complexes formed from solvents with different donor ability were investigated. Recrystallisation of Mn(H(2)daps)(H2O)(0.5) from pyridine and ethanol yields [Mn(H(2)daps)(py)(2)] 1 and [Mn(H(2)daps)(C2H5OH) . (H2O)] 2. Slow evaporation of dichloromethane and methanol solutions of Ni(H(2)daps)(H2O)(1.5)(CH3CN) allows the isolation of single crystals of [Ni-2(H(2)daps)(2)] . CH2Cl2 4 and [Ni-2(H(2)daps)(2)(CH3OH)(2)] . 3 CH3OH . H2O 5, suitable for X-ray diffraction studies. Recrystallisation of 4 from pyridine yields [Ni-2(H(2)daps)(2)(pv)(2)] . CH2Cl2 6, previously characterised by us. This study shows the versatility of the H(4)daps ligand and the influence that the crystallisation solvent can have on the crystal structure of these complexes.

  DOI：

  10.1002/(sici)1521-3749(200002)626:2<506::aid-zaac506>3.0.co;2-e