| 325780-33-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 325780-33-4
• 化学式: C₃₂H₆₂N₂P₂Si₄Sm
• 分子量: 799.507
• InChiKey: VDPGCXVHUCOGEM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 neat (no solvent, solid phase) 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structure of a homoleptic, alkali metal-free lanthanide(II) phosphide complex

  摘要：

  Thermal treatment of [Sm(P(CH[SiMe3](2))(C6H4-2-CH2NMe2)}(2)(THF)] (2) under reduced pressure for several hours leads to complete de-solvation and isolation of the homoleptic phosphide complex [Sm{P(CH[SiMe3](2))(C6H4-2-CH2NMe2)}(2)] (3). X-ray crystallography shows complex 3 to be monomeric, with a four-coordinate, distorted tetrahedral Sm(II) center. The close contacts between Sm and the ipso-carbon atoms of the ligands observed in 2 are absent in 3. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00510-6