[Ir(η2-phenylpyridine(-1H))2(η2-6-methyl-2-hydroxypyridine(-1H))] | 1030021-09-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ir(η2-phenylpyridine(-1H))2(η2-6-methyl-2-hydroxypyridine(-1H))]
• CAS: 1030021-09-0
• 化学式: C₂₈H₂₂IrN₃O
• 分子量: 608.722
• InChiKey: YRODQRBKFHDFOJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-羟基-6-甲基吡啶 、 [(2-phenylpyridine)₂Ir(acetonitrile)₂]NO₃ 在 Et₃N 作用下， 以 乙腈 为溶剂， 以75%的产率得到[Ir(η2-phenylpyridine(-1H))2(η2-6-methyl-2-hydroxypyridine(-1H))]
  参考文献：
  名称：

  Synthesis, structures, and properties of iridium(III) bis-cyclometallated complexes containing three-atom chelates

  摘要：

  Heating of [Ir(eta(2)-ppy)(2)(MeCN)(2)]NO3 (1, ppy = 2-phenylpyridine)in MeCN under reflux afforded [Ir(eta(2)-ppy)(2)(eta(2)-NO3)] (2). Treatment of 1 with 2-mercaptopyridine (Hmp), 6-methyl-2-hydroxypyridine (Hmhp), 6-chloro-2-hydroxypyridine (Hchp), trimethylacetic acid (Htma), benzoic acid (Hbz), 2-methylacrylic acid (Hma), and acetic acid (Hac)in the presence of excess Et3N produced [Ir(eta(2)-ppy) (2)(eta(2)-XZY)] (XZY(-) = mp(-) (3), mhp(-) (4), chp(-) (5), ac(-) (6), bz(-) (7), ma(-) (8), tma(-) (9)). Crystal structures of 2, 3, 7, 8, and 9 have been characterized by X-ray diffraction. The inherent strain contained in the four-member rings, {Ir(eta(2)-XZY)}, is apparently reflected in the long Ir-X and Ir-Y distances. The absorption and emission properties of nearly all the new complexes except 2 show small variations. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.12.009