4-(5-壬基)-吡啶N-氧化物 | 53534-29-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 4-(5-壬基)-吡啶N-氧化物
• 英文名称: 4-(5-Nonyl)-pyridine N-oxide
• 英文别名: 4-nonan-5-yl-1-oxidopyridin-1-ium
• CAS: 53534-29-5
• 化学式: C14H23NO
• 分子量: 221.34
• InChiKey: LQZUVUANAHQVJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  25.5
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933399090

文献信息

• Process for producing ethylidene diacetate and/or acetaldehyde
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0035860A2

  公开（公告）日：1981-09-16

  A process for producing ethylidene diacetate and/or acetaldehyde which comprises causing hydrocarbonylation reaction of methyl acetate or dimethyl ether with carbon monoxide and hydrogen in the presence of a catalyst consisting essentially of (i) as a main component palladium supported on a porous inorganic material and (ii) as a secondary component at least one halide selected from the group consisting of iodides, bromides and mixtures thereof under substantially anhydrous condition is disclosed.

  本发明公开了一种生产二乙酸亚乙酯和/或乙醛的工艺，该工艺包括在催化剂存在的情况下，使乙酸甲酯或二甲醚与一氧化碳和氢发生烃化反应，催化剂主要包括：(i)作为主要成分的支撑在多孔无机材料上的钯，和(ii)作为辅助成分的至少一种选自碘化物、溴化物及其混合物组成的组的卤化物。
• Process for the production of hexafluoropropylene oxide
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0064293A1

  公开（公告）日：1982-11-10

  A process for producing hexafluoropropylene oxide from hexafluoropropylene is described. The process comprises epoxidizing hexafluoropropylene in a two-phase system of an aqueous phase and an organic phase by the use of a hypochlorite as an oxidizing agent, the hypochlorite being dissolved or dispersed in the aqueous phase, in the presence of at least one catalyst selected from the group consisting of (a) quaternary ammonium salts, (b) quaternary phosphonium salts, (c) quaternary arsonium salts, and (d) lipophilic complexing agents for cations contained in the hypochlorite, and also, in the presence or absence of an inorganic base.

  本文描述了一种利用六氟丙烯生产六氟环氧丙烷的工艺。该工艺包括使用次氯酸盐作为氧化剂，在水相和有机相两相体系中对六氟丙烯进行环氧化，次氯酸盐溶解或分散在水相中、在至少一种催化剂的存在下，该催化剂选自 (a) 季铵盐、(b) 季鏻盐、(c) 季砷盐、(d) 次氯酸盐所含阳离子的亲脂络合剂组成的催化剂组，以及在无机碱存在或不存在的情况下。
• Process for producing acetic anhydride
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0055622A1

  公开（公告）日：1982-07-07

  A process for producing acetic anhydride which comprises reacting methyl acetate or dimethyl ether with carbon monoxide in the presence of a catalyst comprising (a) nickel or a nickel compound, (b) at least one halide selected from the group consisting of bromides, iodides and mixtures thereof and (c) at least one organic nitrogen group compound and together with a specific co-catalyst is disclosed. According to this invention acetic anhydride is produces by using highly active non-expensive catalyst and co-catalyst.

  本发明公开了一种生产醋酸酐的工艺，该工艺包括在催化剂存在下使醋酸甲酯或二甲醚与一氧化碳反应，催化剂包括(a)镍或镍化合物，(b)至少一种从溴化物、碘化物及其混合物组成的组中选出的卤化物和(c)至少一种有机氮基团化合物，以及特定的助催化剂。根据本发明，使用高活性非昂贵催化剂和助催化剂可生产醋酸酐。
• Process for producing carboxylic acids
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0065817A1

  公开（公告）日：1982-12-01

  A process for producing a high formation rate carboxylic acid which comprises reacting a hydrocarbyl alcohol with carbon monoxide in the presence of a metal catalyst selected from nickel or cobalt, of a halide and of a two-component promoter.

  一种生产高形成率羧酸的工艺，包括在选自镍或钴的金属催化剂、卤化物和双组分促进剂的存在下，使烃醇与一氧化碳反应。
• Process for producing vinyl acetate
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0048174B1

  公开（公告）日：1984-02-22