(Z)-{1-(phenylthio)-1-(4',4'-dimethyl-oxazolinyl)-2-(p-N,N-dimethylaminophenyl)}ethylene | 139623-33-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (Z)-{1-(phenylthio)-1-(4',4'-dimethyl-oxazolinyl)-2-(p-N,N-dimethylaminophenyl)}ethylene
• CAS: 139623-33-9
• 化学式: C₂₁H₂₄N₂OS
• 分子量: 352.5
• InChiKey: BTAJHZVKALWTMW-RGEXLXHISA-N

反应信息

• 作为反应物：
  描述：

  双(乙腈)氯化钯(II) 、 (Z)-{1-(phenylthio)-1-(4',4'-dimethyl-oxazolinyl)-2-(p-N,N-dimethylaminophenyl)}ethylene 以 二氯甲烷 为溶剂， 以98%的产率得到(Z)-{1-(phenylthio)-1-(4',4'-dimethyl-oxazolinyl)-2-(p-N,N-dimethylaminophenyl)}ethylene palladium dichloride complex
  参考文献：
  名称：

  Synthesis and nonlinear optical properties of new bimetallic iron/palladium complexes

  摘要：

  Two new ferrocenyl derivatives. (Z)-[1-(benzylthio)-1-(4',4'-dimethyl-oxazolinyl)-2-ferrocenyl]ethylene (3) and (Z)-[1-(benzylsulfino)-1-(4',4'-dimethyloxazolinyl)-2-ferrocenyl]ethylene (4) have been synthesized. On complexation with PdCl2 these yield new bimetallic complexes 5 and 6 respectively. Non-linear optical properties measured by the EFISH technique show an enhanced molecular hyperpolarizability upon complexation. leading to higher values for beta-0.

  DOI：

  10.1016/0022-328x(91)86414-l