2-(2,6-dimethylpyridin-2-yl)benzo[d]thiazole | 43193-03-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-(2,6-dimethylpyridin-2-yl)benzo[d]thiazole
• 英文别名: 2-(2,6-dimethylpyridin-4-yl)benzo[d]thiazole；4-(Benzothiazol-2-yl)-2,6-dimethylpyridin；2-(2,6-Dimethylpyridin-2-yl)benzothiazol；2-(2,6-dimethyl-pyridin-4-yl)-benzothiazole；4-(Benzothiazol-2-yl)-2,6-dimethylpyridine；2-(2,6-dimethylpyridin-4-yl)-1,3-benzothiazole
• CAS: 43193-03-9
• 化学式: C₁₄H₁₂N₂S
• 分子量: 240.329
• InChiKey: CPUMZISRFNZWPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2,6-dimethylpyridin-2-yl)benzo[d]thiazole 、 氟硼酸铵 在 原甲酸三甲酯 作用下， 生成 4-(benzo[d]thiazol-2-yl)-1,2,6-trimethylpyridin-1-ium tetrafluoroborate
  参考文献：
  名称：

  HETEROARYL-PYRIDINIUM COMPOUND AND REDOX FLOW BATTERY COMPRISING THE SAME

  摘要：

  Provided are a heteroaryl-pyridinium compound and a redox flow battery including the same. The redox flow battery includes a positive electrode cell including a positive electrode and a posolyte solution; a negative electrode cell including a negative electrode and a negolyte solution; and a separator disposed between the positive electrode cell and the negative electrode cell. The negolyte solution is the electrolyte solution for a redox flow battery.

  公开号：

  US20220332712A1
• 作为产物：
  描述：

  2,6-dimethyl-4-(2-benzothiazolyl)pyrylium perchlorate 在 ammonium hydroxide 作用下， 生成 2-(2,6-dimethylpyridin-2-yl)benzo[d]thiazole
  参考文献：
  名称：

  Synthesis and reactions of 4-(benzothiazol-2-yl)-2,6-dimethylpyrylium perchlorate

  摘要：

  DOI：

  10.1007/bf00471701

文献信息

• Nitro-Methyl Redox Coupling: Efficient Approach to 2-Hetarylbenzothiazoles from 2-Halonitroarene, Methylhetarene, and Elemental Sulfur
  作者：Thanh Binh Nguyen、Ludmila Ermolenko、Ali Al-Mourabit

  DOI：10.1021/ol401944a

  日期：2013.8.16

  A simple, straightforward, and atom economic approach to 2-hetarylbenzothiazoles starting from 2-halonitroarene, methylhetarene, and elemental sulfur under mild conditions is described. The method is highlighted by the direct redox nitro-methyl reaction for carbon-nitrogen bond formation without an added oxidizing or reducing agent.