2-(o-Tolyl)-4,5-dimethylpyridin | 59463-71-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(o-Tolyl)-4,5-dimethylpyridin
• 英文别名: 4,5-dimethyl-2-o-tolyl-pyridine；4,5-Dimethyl-2-(2-methylphenyl)pyridine
• CAS: 59463-71-7
• 化学式: C₁₄H₁₅N
• 分子量: 197.28
• InChiKey: IXIRNVAMPRBXIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• [EN] PROCESS FOR FORMING A CARBON-CARBON BOND<br/>[FR] PROCÉDÉ DE FORMATION D'UNE LIAISON CARBONE-CARBONE
  申请人：UNIV MANCHESTER

  公开号：WO2019215426A1

  公开（公告）日：2019-11-14

  A process for forming a carbon-carbon bond to couple an aryl or heteroaryl group of a first compound with an aryl or heteroaryl group of a second compound, the process comprising reacting the first compound with the second compound in the presence of a catalytically effective amount of a neutral or cationic ruthenium(II) catalyst of formula (I):

  一种形成碳-碳键的工艺，用于将第一化合物中的芳基或杂芳基团与第二化合物中的芳基或杂芳基团偶联，该工艺包括在存在公式(I)的中性或阳离子钌(II)催化剂的催化有效量下，使第一化合物与第二化合物反应：
• Organic electroluminescent materials and devices
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20200308204A1

  公开（公告）日：2020-10-01

  A compound comprising a first bidentate ligand L A , wherein L A comprises a structure of Formula I; wherein Z is selected from the group consisting of O, S, NR, BR, CR K R L , SiR K R L , —CR K R L CR M R N —, —SiR K R L SiR M R N —, —CR K R L O—, —SiR K R L O—, and —CR K ═CR L —; wherein ring A, ring B, and ring C are each independently a 5-membered carbocyclic ring, 5-membered heterocyclic ring, 6-membered carbocyclic ring or 6-membered heterocyclic ring; wherein L A is coordinated to a metal M forming a 5-membered chelate ring; wherein M is selected from the group consisting of Ir, Pt, Pd, Ru, Rh, Os, Re, Cu, Ag, and Au; wherein R A , R B , and R C each represent mono to the maximum allowable substitution, or no substitution; wherein each R, R K , R L , R M , R N , R A , R B , and R C is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein M is optionally coordinated to one or more other ligands; wherein any two substituents are optionally joined or fused together to form a ring; and with the provision that L A does not comprise the following structure:

  一种化合物，包括第一双齿配体LA，其中LA包括结构式I的结构；其中Z选择自O、S、NR、BR、CRKRL、SiRKRL、—CRKRLCRMRN—、—SiRKRLSiRMRN—、—CRKRLO—、—SiRKRLO—和—CRK═CRL—组成的群体；其中环A、环B和环C分别独立为5元碳环、5元杂环、6元碳环或6元杂环；其中LA配位于金属M形成5元螯合环；其中M选择自Ir、Pt、Pd、Ru、Rh、Os、Re、Cu、Ag和Au组成的群体；其中RA、RB和RC分别表示单取代至最大允许取代，或无取代；其中每个R、RK、RL、RM、RN、RA、RB和RC独立地是氢或从氘、卤素、烷基、环烷基、杂原子烷基、芳基烷基、烷氧基、芳氧基、氨基、硅基、硼基、烯基、环烯基、杂原子烯基、炔基、芳基、杂芳基、酰基、羧酸、醚、酯、腈、异腈、硫基、亚硫基、砜基、膦基等组成的取代基中选择；其中M可以选择与一个或多个其他配体配位；其中任意两个取代基可以选择连接或融合在一起形成环；并且提供LA不包括以下结构：
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20210399236A1

  公开（公告）日：2021-12-23

  Provided are organometallic compounds. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

  提供有机金属化合物。还提供了含有这些有机金属化合物的配方。进一步提供了利用这些有机金属化合物的OLED和相关消费品。
• Organic electroluminescent materials and device
  申请人：Universal Display Corporation

  公开号：US11038115B2

  公开（公告）日：2021-06-15

  A compound including a first ligand LA of Formula I, useful as an emitter in OLEDs is disclosed.

  一种化合物，包括式 I 的第一配体 LA、 的第一配体 LA 的化合物。
• Organic eletroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：EP2874192B1

  公开（公告）日：2017-05-10