3,4,6-Trimethoxy-2-[2-methyl-3-oxo-1-(2,4,5-trimethoxy-phenyl)-butyl]-benzaldehyde | 86702-03-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4,6-Trimethoxy-2-[2-methyl-3-oxo-1-(2,4,5-trimethoxy-phenyl)-butyl]-benzaldehyde
• CAS: 86702-03-6
• 化学式: C₂₄H₃₀O₈
• 分子量: 446.497
• InChiKey: PEKARRYUNVWQOG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  3,4,6-Trimethoxy-2-[2-methyl-3-oxo-1-(2,4,5-trimethoxy-phenyl)-butyl]-benzaldehyde 在 tris(triphenylphosphine)rhodium(l) chloride 作用下， 以 苯 为溶剂， 以12%的产率得到3-Methyl-4-(2,4,5-trimethoxy-phenyl)-4-(2,3,5-trimethoxy-phenyl)-butan-2-one
  参考文献：
  名称：

  Isolation and structure of magnosalin and magnoshinin, new neolignans from Magnolia saliciforia Maxim.

  摘要：

  The structures of magnosalin and magnoshinin, new neolignans isolated from buds of Magnolia salicifolia MAXIM., were determined to be 1 and 4, respectively, on the basis of chemical and spectroscopic evidence.

  DOI：

  10.1248/cpb.31.1112
• 作为产物：
  描述：

  magnoshinin 在 四氧化锇 、 过碘酸 作用下， 生成 3,4,6-Trimethoxy-2-[2-methyl-3-oxo-1-(2,4,5-trimethoxy-phenyl)-butyl]-benzaldehyde
  参考文献：
  名称：

  Isolation and structure of magnosalin and magnoshinin, new neolignans from Magnolia saliciforia Maxim.

  摘要：

  The structures of magnosalin and magnoshinin, new neolignans isolated from buds of Magnolia salicifolia MAXIM., were determined to be 1 and 4, respectively, on the basis of chemical and spectroscopic evidence.

  DOI：

  10.1248/cpb.31.1112