5-Methyl-5-phenylhexansaeuremethylester | 121532-74-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-Methyl-5-phenylhexansaeuremethylester
• 英文别名: Methyl 5-methyl-5-phenylhexanoate
• CAS: 121532-74-9
• 化学式: C₁₄H₂₀O₂
• 分子量: 220.312
• InChiKey: RAPMFPUNQGTSGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-Methyl-5-phenylhexansaeuremethylester 在 PPA 作用下， 生成 5,5-Dimethyl-6,7-dihydro-5H-benzocyclohepten
  参考文献：
  名称：

  Three-membered rings. III. Ultraviolet spectral evidence of a stereochemical bias in rigid p-nitrophenylcyclopropanes

  摘要：

  DOI：

  10.1021/jo00979a015
• 作为产物：
  描述：

  3-Methyl-3-phenyl-1-butyl-p-toluolsulfonat 在 氢氧化钾 作用下， 生成 5-Methyl-5-phenylhexansaeuremethylester
  参考文献：
  名称：

  Three-membered rings. III. Ultraviolet spectral evidence of a stereochemical bias in rigid p-nitrophenylcyclopropanes

  摘要：

  DOI：

  10.1021/jo00979a015

文献信息

• NOVEL AROMATIC THIO COMPOUNDS AS RECEPTOR MODULATORS
  申请人：Allergan, Inc.

  公开号：US20140171393A1

  公开（公告）日：2014-06-19

  The present invention relates to novel aromatic thio derivatives, processes for preparing them, pharmaceutical compositions containing them and their use as pharmaceuticals as modulators of sphingosine-1-phosphate receptors.

  本发明涉及新型芳香硫代衍生物，制备它们的方法，含有它们的药物组合物以及它们作为调节鞘氨醇-1-磷酸受体的药物的用途。
• COMPOSITION AND ORGANIC PHOTOELECTRIC CONVERTER
  申请人：Uetani Yasunori

  公开号：US20100193033A1

  公开（公告）日：2010-08-05

  A composition containing a polymer having a structural unit represented by the following formula (1) and a structural unit represented by the following formula (2), and a fullerene with a carbon number of 70 or more or a fullerene derivative having a fullerene skeleton with a carbon number of 70 or more: wherein, Q, R, R 1 and R 2 each independently denote a hydrogen atom, and so on.
• Fullerene Multi-Adduct Compositions
  申请人：Hummelen Jan C.

  公开号：US20110089380A1

  公开（公告）日：2011-04-21

  One aspect of the invention relates to compositions comprising one or more fullerene derivatives that comprise one or more covalent addends. In certain embodiments, the fullerene derivatives are selected from the group consisting of methanofullerene derivatives, Prato adduct fullerene derivatives, Diels-Alder fullerene derivatives, diazoline fullerene derivatives, Bingel fullerene derivatives, ketolactam fullerene derivatives, and azafulleroid fullerene derivatives. In certain embodiments, the fullerenes are C60 or C70 or a mixture thereof. The invention also relates to semiconductors, photodiodes, solar cells, photodectectors, and transistors comprising one or more fullerene derivatives that comprise one or more covalent addends.
• COMPOSITION, AND ORGANIC PHOTOELECTRIC CONVERSION ELEMENT COMPRISING SAME
  申请人：Uetani Yasunori

  公开号：US20110130588A1

  公开（公告）日：2011-06-02

  Disclosed is a composition produced by reacting a fullerene derivative with a reducing agent. The composition is preferably produced by adding a reducing agent to a composition comprising a fullerene derivative and a solvent to cause the reaction of the fullerene derivative and the reducing agent. The reducing agent is preferably a trivalent phosphorus compound.
• FULLERENE DERIVATIVE
  申请人：Uetani Yasunori

  公开号：US20120111411A1

  公开（公告）日：2012-05-10

  An organic photoelectronic conversion element having a sufficiently high open-circuit voltage can be produced by using a fullerene derivative comprising a structure represented by formula (1) and one or more structures selected from the group consisting of a structure represented by formula (2-1) and a structure represented by formula (2-2).