perfluoro-3H,4H-heptane | 142347-09-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: perfluoro-3H,4H-heptane
• 英文别名: 1,1,1,2,2,3,3,4,5,6,6,7,7,7-Tetradecafluoroheptane
• CAS: 142347-09-9
• 化学式: C₇H₂F₁₄
• 分子量: 352.071
• InChiKey: MQQLAYMCXDAYFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  14

文献信息

• Terephthalate stabilizers for fluoroolefins
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2420546A2

  公开（公告）日：2012-02-22

  The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one terephthalate or a mixture thereof with at least one of ascorbic acid and nitromethane. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

  本公开涉及由至少一种氟烯烃和有效量的稳定剂组成的组合物，稳定剂由至少一种对苯二甲酸盐或其混合物与抗坏血酸和硝基甲烷中的至少一种组成。这种稳定组合物可用于制冷、空调、冷风机和热泵等冷却设备，也可用作发泡剂、溶剂、气溶胶推进剂、灭火剂和消毒剂。
• Phosphorus-containing stabilizers for fluoroolefins
  申请人：E.I. Du Pont De Nemours And Company

  公开号：EP2410032A2

  公开（公告）日：2012-01-25

  The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one phosphorus-containing compound selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, and organophosphates. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

  本公开涉及的组合物包含至少一种氟烯烃和有效量的稳定剂，稳定剂包含至少一种含磷化合物，该化合物选自由硫代磷酸盐、丁基化三苯基硫代磷酸盐和有机磷酸盐组成的组。这种稳定组合物可用于制冷、空调、冷却器和热泵等冷却设备，也可用作发泡剂、溶剂、气溶胶推进剂、灭火剂和消毒剂。
• Compositions comprising tetrafluoropropene and methods of use thereof
  申请人：THE CHEMOURS COMPANY FC, LLC

  公开号：US10035940B2

  公开（公告）日：2018-07-31

  The present invention relates to a composition comprising HFO-1234yf, or trans-HFO-1234ze, or a mixture thereof; HFC-32; and HFC-152a, HFO-1243zf, or a mixture thereof, wherein said composition is selected from the group consisting of: (I) a first composition, wherein said HFO-1234yf or trans-HFO-1234ze or a mixture thereof is at least 56 weight percent of said first composition; (II) a second composition, wherein said HFC-32 is at most 29 weight percent of said second composition; (III) a third composition, wherein said HFC-152a is at least 56 weight percent said third composition; (IV) a fourth composition, wherein said HFC-32 is at least 56 weight percent of said fourth composition; (V) a fifth composition comprising trans-HFO-1234ze, HFC-32, and HFC-152a, HFO-1243zf, or a mixture thereof; and (VI) a sixth composition, wherein said HFO-1243zf or mixture thereof with HFC-152a is at most 20 weight percent of said sixth composition.

  本发明涉及一种由 HFO-1234yf 或反式 HFO-1234ze 或其混合物、HFC-32 和 HFC-152a、HFO-1243zf 或其混合物组成的组合物，其中所述组合物选自以下组别： (I) 第一种组合物，其中所述 HFO-1234yf 或反式 HFO-1234ze 或其混合物至少占所述第一种组合物的 56%； (II) 第二种组合物，其中所述 HFC-32 至多占所述第二种组合物的 29%； (III) 第三种组合物，其中所述 HFC-152a 至少占所述第三种组合物的 56%； (IV) 第四种组合物，其中所述 HFC-32 占所述第四种组合物的至少 56% 重量比； (V) 第五种组合物，包括反式-HFO-1234ze、HFC-32 和 HFC-152a、HFO-1243zf 或其混合物；以及 (VI) 第六种组合物，其中所述 HFO-1243zf 或其与 HFC-152a 的混合物最多占所述第六种组合物的 20%。
• Epoxide and fluorinated epoxide stabilizers for fluoroolefins
  申请人：The Chemours Company FC, LLC

  公开号：US10550302B2

  公开（公告）日：2020-02-04

  The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

  本发明涉及由至少一种氟烯烃和一定量的稳定剂组成的组合物，稳定剂可以是环氧化物、氟化环氧化物或氧杂环丁烷，也可以是它们与其他稳定剂的混合物。这种稳定组合物可用于制冷、空调、冷风机和热泵等冷却设备，也可用作发泡剂、溶剂、气溶胶推进剂、灭火剂和消毒剂。
• Compositions containing difluoromethane, tetrafluoropropene, and carbon dioxide and uses thereof
  申请人：THE CHEMOURS COMPANY FC, LLC

  公开号：US11306233B2

  公开（公告）日：2022-04-19

  In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO2. The compositions are useful as refrigerants in processes to produce cooling and heating, in methods for replacing refrigerant R-410A, and in refrigeration, air conditioning or heat pump systems. These inventive compositions match cooling capacity for R-410A within ±10% with GWP less than 400 or less than 300.

  本发明公开了制冷剂组合物。这些组合物包括主要由 HFC-32、HFO-1234yf 和 CO2 组成的制冷剂混合物。这些组合物可作为制冷剂用于制冷和制热过程、替代制冷剂 R-410A 的方法以及制冷、空调或热泵系统。这些发明的组合物与 R-410A 的冷却能力匹配度在±10%以内，全球升温潜能值小于 400 或小于 300。