N,N'-dimesityl-1-(4-nitrophenyl)ethan-1,2-diamine | 1448898-56-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dimesityl-1-(4-nitrophenyl)ethan-1,2-diamine
• CAS: 1448898-56-3
• 化学式: C₂₆H₃₁N₃O₂
• 分子量: 417.551
• InChiKey: MZGMDHOQNAXPEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.71
• 重原子数：
  31.0
• 可旋转键数：
  7.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  67.2
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  N,N'-dimesityl-1-(4-nitrophenyl)ethan-1,2-diamine 、 原甲酸三乙酯 在 氯化铵 作用下， 反应 8.0h， 以82%的产率得到4-(4-nitrophenyl)-1,3-bis-(2,4,6-trimethylphenyl)-4,5-dihydro-3H-imidazolium chloride
  参考文献：
  名称：

  Synthesis and characterization of a 4-nitrophenyl functionalized NHC ligand and its palladium(II) complex

  摘要：

  The synthesis and characterization of a novel pyridine coordinated dichloridopalladium(II) NHC complex is described. This compound possesses a saturated NHC ligand that is substituted with a para-nitrophenyl function in the 4-position of the NHC backbone. It is accessible in four steps with overall good yields starting from 4-nitro acetophenone. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.05.025
• 作为产物：
  描述：

  N1,N2-dimesityl-1-(4-nitrophenyl)ethane-1,2-diimine 在 sodium cyanoborohydride 、 盐酸 作用下， 以 水 为溶剂， 反应 1.0h， 以85%的产率得到N,N'-dimesityl-1-(4-nitrophenyl)ethan-1,2-diamine
  参考文献：
  名称：

  Synthesis and characterization of a 4-nitrophenyl functionalized NHC ligand and its palladium(II) complex

  摘要：

  The synthesis and characterization of a novel pyridine coordinated dichloridopalladium(II) NHC complex is described. This compound possesses a saturated NHC ligand that is substituted with a para-nitrophenyl function in the 4-position of the NHC backbone. It is accessible in four steps with overall good yields starting from 4-nitro acetophenone. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.05.025