Methyl difluoro[(thiophen-2-yl)sulfanyl]acetate | 184949-68-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Methyl difluoro[(thiophen-2-yl)sulfanyl]acetate
• 英文别名: methyl 2,2-difluoro-2-thiophen-2-ylsulfanylacetate
• CAS: 184949-68-6
• 化学式: C₇H₆F₂O₂S₂
• 分子量: 224.252
• InChiKey: BFDJEUSNAQDVHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  79.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  噻吩 、 methoxycarbonyldifluoromethylsulfenyl chloride 在 四氯化锡 作用下， 以 氯仿 为溶剂， 以77%的产率得到Methyl difluoro[(thiophen-2-yl)sulfanyl]acetate
  参考文献：
  名称：

  ?-Methoxycarbonyl-containing polyflouoalkylsulfenyl chlorides

  摘要：

  New alpha-methoxycarbonyl-containing polyfluoroalkylsulfenyl chlorides were obtained. Reactions of sulfenyl chlorides containing primary, secondary and tertiary alpha-methoxycarbonyl-polyfluoroalkyl groups at the sulfur atom with some unsaturated, carbonyl, aromatic, and heteroaromatic compounds were studied.

  DOI：

  10.1007/bf01431803

文献信息

• ?-Methoxycarbonyl-containing polyflouoalkylsulfenyl chlorides
  作者：A. Yu. Sizov、V. M. Rogovik、A. F. Kolomiets、A. V. Fokin

  DOI：10.1007/bf01431803

  日期：1996.7

  New alpha-methoxycarbonyl-containing polyfluoroalkylsulfenyl chlorides were obtained. Reactions of sulfenyl chlorides containing primary, secondary and tertiary alpha-methoxycarbonyl-polyfluoroalkyl groups at the sulfur atom with some unsaturated, carbonyl, aromatic, and heteroaromatic compounds were studied.