| 185827-47-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 185827-47-8；126752-96-3
• 化学式: C₆H₅O₃P*H₂O₂V
• 分子量: 241.034
• InChiKey: GKZGKOAITWLXHL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.72
• 重原子数：
  13.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  111.76
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  以 水 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Hydrothermal synthesis and structural characterization of a tubular oxovanadium organophosphonate, (H3O)[(V3O4)(H2O)(PhPO3)3]·xH2O(x = 2.33)

  摘要：

  在180°C下，KVO3、PhPO3H2和水发生水热反应116小时，生成管状混合价VV/VIV聚合物（H3O）[(V3O4)(H2O) (PhPO3)3]·xH2O（x = 2.33）。

  DOI：

  10.1039/a804864i
• 作为产物：
  描述：

  苯膦酸 、 水 、 vanadia 以 水 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Hydrothermal synthesis and structural characterization of a tubular oxovanadium organophosphonate, (H3O)[(V3O4)(H2O)(PhPO3)3]·xH2O(x = 2.33)

  摘要：

  在180°C下，KVO3、PhPO3H2和水发生水热反应116小时，生成管状混合价VV/VIV聚合物（H3O）[(V3O4)(H2O) (PhPO3)3]·xH2O（x = 2.33）。

  DOI：

  10.1039/a804864i

文献信息

• Intercalation of Alcohols into Layered Vanadyl Phosphonates
  作者：P. Gendraud、M.E. de Roy、J.P. Besse

  DOI：10.1006/jssc.1993.1314

  日期：1993.10

  Layered vanadyl organophosphonates of general formula VO(RPO3) · nH2O, where R = CH3, C2H5, C6H5, were synthesized in alcoholic solution. Intercalation of alkanols, CnH2n+1OH (n = 1 - 4), and benzyl alcohol with each phosphonate previously prepared is reported and discussed. Samples and intercalation compounds were characterized for their X-ray powder diffraction patterns, IR spectra, and TGA analyses

  在醇溶液中合成了通式为VO（R PO 3）· n H 2 O的层状钒基有机膦酸酯，其中R＝ CH 3，C 2 H 5，C 6 H 5。据报道和讨论了链烷醇，C n H 2 n +1 OH（n = 1-4）和苯甲醇与先前制备的每种膦酸酯的嵌入。对样品和插层化合物的X射线粉末衍射图，红外光谱和TGA分析进行了表征。
• Johnson, Jack W.; Jacobson; Brody, Inorganic Chemistry, 1984, vol. 23, # 24, p. 3842 - 3844
  作者：Johnson, Jack W.、Jacobson、Brody、Lewandowski

  DOI：——

  日期：——
• Synthetic pathways to vanadyl organophosphonates through aqueous media
  作者：P. Gendraud、L. Bigey、M.E. de Roy、J.P. Besse

  DOI：10.1016/s0025-5408(96)00164-x

  日期：1997.1

  Synthesis of vanadyl(IV) organophosphonates VORPO(3) . nH(2)O (with R = CH3, C2H5, C6H5) has been investigated by reaction of VOSO4 . 5H(2)O + RPO(3)H(2) under refluxing conditions in aqueous media. The influence of different parameters is discussed, and compounds are characterized by X-ray powder diffraction, TGA, IR, XANES, and EXAFS. For example, three crystallographic forms of VOC6H5PO3 .2H2O obtained differ from each other in the location of the trans water molecule in the layered structure.
• Chen, Qin; Salta, Jośe; Zubieta, Jon, Inorganic Chemistry, 1993, vol. 32, # 21, p. 4485 - 4486
  作者：Chen, Qin、Salta, Jośe、Zubieta, Jon

  DOI：——

  日期：——
• Intercalation Reactions of Layered Vanadyl Organophosphonates with Alkylamines
  作者：P. Gendraud、M. E. de Roy、J. P. Besse

  DOI：10.1021/ic960238h

  日期：1996.1.1

  Layered vanadyl organophosphonates VORPO(3) . xH(2)O were brought into contact with primary alkylamines CnH2n+1NH2 (n = 3-6). Intercalation compounds have been characterized by their basal spacings, thermogravimetric analysis (TGA), XANES, and IR spectra. Regardless of the starting vanadyl phosphonate, a plot of the interlayer distances of the intercalates vs the number of carbon atoms (n(c)) in the alkyl chain of the amine indicates that amine molecules were packed in the interlamellar space either as bilayer or as an interdigitated monolayer, depending on n(c). Hydrolysis of the phosphonate groups, oxidation of vanadium atoms, and the nature of the final products are described.