Cu(OAc)(bis(2,6-dimethylphenyl)penta-2,4-diiminato) | 1123299-02-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu(OAc)(bis(2,6-dimethylphenyl)penta-2,4-diiminato)
• 英文别名: Cu(OAc)(N,N'-bis(2,6-Me2C6H3)nacnac)
• CAS: 1123299-02-4
• 化学式: C₂H₃O₂*C₂₁H₂₅N₂*Cu
• 分子量: 428.034
• InChiKey: URCHHHZHDSYHSI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.76
• 重原子数：
  28.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  64.85
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  [N(2,6-dimethylphenyl)C(Me)]2CH2 、 copper diacetate 以 甲醇 、 二氯甲烷 为溶剂， 生成 Cu(OAc)(bis(2,6-dimethylphenyl)penta-2,4-diiminato)
  参考文献：
  名称：

  Syntheses and structures of bis(2,6-xylyl-nacnac) copper(I) complexes

  摘要：

  The copper(I) complexes {(bis-2,6-dimethylphenyl-penta-2,3-diiminato)Cu}(2)(mu-toluene), 3 has been prepared and its reactivity against Lewis bases and nitrous oxide investigated. Complex 3 crystallizes as a toluene-bridged dimer and forms mono- and dinuclear benzene adducts in C6D6 solution. It does not coordinate excess THF, but reacts quantitatively with 1 equiv. of acetonitrile. Reaction with 2,6-xylyl isonitrile yields (bis-2,6-dimethylphenyl-penta-2,3-diiminato) Cu(2,6-xylyl isonitrile), 5, (nu(CN) = 2123 cm (1)), which was characterized by an X-ray diffraction study. Complex 3 does not react with nitrous oxide in either C6D6 solution (5 days 50 degrees C) or in diethyl ether (13 days at ambient temperature). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.008