trans-[Ru(NH3)4(P(OC6H5)3)(H2O)](2+) | 115862-44-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-[Ru(NH3)4(P(OC6H5)3)(H2O)](2+)
• 英文别名: trans-{Ru(NH3)4(P(OPh)3)(H2O)}(2+)
• CAS: 115862-44-7
• 化学式: C₁₈H₂₉N₄O₄PRu
• 分子量: 497.496
• InChiKey: XRBULTDZNKZUCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[Ru(NH3)4(P(OC6H5)3)(H2O)](2+) 、 水 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  Selective Photolabilization in trans-[Ru(NH₃)₄(P(III))H₂O]²⁺ and trans-[Ru(NH₃)₄(P(OR)₃)₂]²⁺ Complexes (P(III) = P(OR)₃, P(R)₃)

  摘要：

  Irradiation in the LF bands (1)A(1) --> (1)E(1) and (1)A(1g) --> (1)A(2g), (1)E(g) leads to NH3 photolabilization of trans-[Ru(NH3)(4)(P(III))H2O](2+) complexes and to NH3 and P(III) photolabilization of trans-[Ru(NH3)(4)(P(III))(2)](2+) species. For both series of complexes Phi(NH3) has essentially the same experimental value of 0.34 +/- 0.03 mol/einstein. The Phi(P(III)) values for the bis(phosphane) complexes trans-[Ru(NH3)(4)(P(III))(2)](2+) are in the 0.034-0.070 range for P(III) = P(OCH3)(3) and P(OC2H4Cl)(3). No clear relationship could be established between the cone angle theta of the phosphane or the formal potential E degrees'(Ru(III)/Ru(II)) and the corresponding Phi(NH3) and Phi(P(III)) data for the complexes studied. The NH3 ligand is selectively photolabilized when the trans-[Ru(NH3)(4)(P(III))(2)](2+) and the trans-[Ru(NH3)(4)(P(III))H2O](2+) species are irradiated with energies corresponding to the (1)A(1g) --> (1)A(2g) and (1)A(1) --> (1)A(2) transitions.

  DOI：

  10.1021/ic9509847

文献信息

• Ruthenium(II) tetraammines, a useful model to compare trans-effect and trans-influence of phosphanes
  作者：José Cardoso do Nascimento Filho、José Milton de Rezende、Benedito dos Santos Lima Neto、Douglas Wagner Franco

  DOI：10.1016/s0020-1693(00)82016-2

  日期：1988.5
• Trans-effect and trans-influence series for phosphanes in octahedral environment: A guide for design of new catalysts
  作者：José Cardoso do Nascimento Filho、Joacy Batista de Lima、Benedito dos Santos Lima Neto、Douglas Wagner Franco

  DOI：10.1016/0304-5102(94)00018-2

  日期：1994.6

  By a kinetic approach, the trans-effects and trans-influences of nineteen tertiary phosphane ligands were evaluated for a hexacoordinated d6-low spin metal center. Plots of specific rate constants versus formal potentials for Ru(III)/Ru(II) couples provide a simple, reliable and efficient method to predict phosphane reactivity and are useful as a guide for design of new catalysts.