chloro-tris(trimethylphosphine)copper | 40696-72-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: chloro-tris(trimethylphosphine)copper
• 英文别名: tris(trimethylphosphino)copper(I) chloride；chlorotris(trimethylphosphine)copper(I)
• CAS: 40696-72-8
• 化学式: C₉H₂₇ClCuP₃
• 分子量: 327.234
• InChiKey: YXNQQNDCLFZDLY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.76
• 重原子数：
  14.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  chloro-tris(trimethylphosphine)copper 、 bis(tetraethylammonium)tris(selenido)tertbutylthiolatoniobate(V) 在 O₂ 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以10%的产率得到
  参考文献：
  名称：

  硫属铌酸盐作为制备新型异质双金属铌硬币金属硫属元素团簇的起始材料

  摘要：

  In the presence of phosphine chalcogenoniobates such as Li-3[NbS4] . 4CH(3)CN (I), (NEt4)(4)[Nb6S17] . 3 CH3CN (II) and (NEt4)(2)[NbE3' ((EBu)-Bu-t)] (IIIa: E ' =E=S. IIIb: E = Se, E ' = S; III c: E = E ' = Se) respectively react with copper and gold salts to give a number of new heterobimetallic niobium copper(gold) chalcogenide clusters. These clusters show metal chalcogenide units already known from the complex chemistry of the tetrachalcogenometalates [ME4](n-)(M=V,n=3, E=S; M=Mo, W, n=2, E=S, Se). The compounds 1-8 owe a central tetrahedral [NbE4] structural unit, which coordinates eta (2) from two to five coinage metal atoms, employing the chalcogenide atoms of the [NbE4] edges. The compounds 9-11 have a [M-2' Nb2E4] (M '= Cu, Au) heterocubane unit in common, involving a metal metal bond between the niobium atoms, while the compounds 12 and 13 show a complete and 14 an incomplete [M-3' NbE3X] heterocubane structure (X = Cl, Br). 15 consists of a Cu6Nb2 cube with the six planes capped by mu (4) bridging selenide ligands forming an octahedra. The compounds 1-15 are listed below:(NEt4)(x)(1)[Cu2NbSe2S2(dppe)(2)] . 2DMF (1), [Cu3NbS4(PPh3)(4)] (2), [Au3NbSe4(PPh3)(4)] . Et2O (3), [Cu4NbS4Cl(PCY3)(4)] (4), [Cu4NbS4Cl((PBu3)-Bu-t)(4)] . 0.5 DMF (5), (Cu4NbSe4(NCS)((PBu3)-Bu-t)(4)] . DMF (6), [Cu4NbS4(NCS)(dppm)(4)] . Et2O (7), [Cu5NbSe4Cl2(dppm)(4)] . 3DMF (8), [Cu2Nb2S4Cl2(PMe3)(6)] . DMF (9), [Au2Nb2Se4Cl2(PMe3)(6)] . DMF (10), (NEt4)(2)[Cu3Nb2S4(NCS)(5)(dppm)(2)(dmf)] . 4DMF (11), [Cu3NbS3Br(PPh3)(3)(dmf)(3)]Br . [CuBr(PPh3)(3)] . PPh3 . OPPh3 . 3 DMF (12), [Cu3NbS3Cl2(PPh3)(3)(dmf)(2)] . 1.5 DMF (13), (NEt4)[Cu3NbSe3Cl3(dmf)(3)] (14), [Cu6Nb2Se6O2(PMe3)(6)] (15). The structures of these compounds were obtained by X-ray single crystal structure analysis.

  DOI：

  10.1002/1521-3749(200109)627:9<2232::aid-zaac2232>3.0.co;2-t

文献信息

• Silyl-, stannyl- and plumbyl-copper compounds containing chelating and monodentate phosphine ligands
  作者：Hans-F. Klein、J. Montag、U. Zucha、Ulrich Flörke、Hans-J. Haupt

  DOI：10.1016/s0020-1693(00)91906-6

  日期：1990.11

  Abstract Syntheses and properties of metalmetal bonded complexes of the type L3CuER3 are described, 1: ER3Si(SiMe3)3; 3 LCH3C(CH2PPh2)3L3triphos. 2: ER3SnCl3; LPMe3. 3: ER3SnCl2I; LPMe3. 4: ER3SnCl3; 3 L=triphos. 5: ER3SnMe3; 3 L=triphos. 6: ER3SnPh3; LPMe3 7: ER3SnPh3; LPPh3. 8: ER3SnPh3; 3 L=triphos. 9: ER3PbPh3; 3 L=triphos. 10: ER3PbMe3; 3 L=triphos. Insertion of CS2 into the

  摘要描述了L3CuER3类型的金属与金属键合的配合物的合成和性能：1：ER3Si（SiMe3）3；3LCH3C（CH2PPh2）3L3三phos。2：ER3SnCl3; LPMe3。3：ER3SnCl2I; LPMe3。4：ER 3 -SnCl 3；3 L =三磷酸。5：ER3SnMe3；3 L =三磷酸。6：ER3SnPh3；LPMe37：ER3SnPh3；LPPh3。8：ER3SnPh3；3 L =三磷酸。9：ER3PbPh3；3 L =三磷酸。10：ER3PbMe3；3 L =三磷酸。将CS2插入1的CuSi键中可得到L3CuS2CSi（SiMe3）3（11），而将5可获得L3CuS2CSnMe3·CS2（12）。化合物12在空间群P21 / c中以a = 15.062（5），b = 13.632（3），c = 22.706（7）A，β= 91.50（2）°，V
• 10.1002/1521-3773(20011203)40
  作者：Lorenz、Fenske

  DOI：10.1002/1521-3773(20011203)40

  日期：——
• Otto, Heiko; Werner, Helmut, Chemische Berichte, 1987, vol. 120, p. 97 - 104
  作者：Otto, Heiko、Werner, Helmut

  DOI：——

  日期：——