1,4-Bis-(p-vinylbenzoylamido)anthrachinon | 29822-57-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4-Bis-(p-vinylbenzoylamido)anthrachinon
• 英文别名: 4-ethenyl-N-[4-[(4-ethenylbenzoyl)amino]-9,10-dioxoanthracen-1-yl]benzamide
• CAS: 29822-57-9
• 化学式: C₃₂H₂₂N₂O₄
• 分子量: 498.538
• InChiKey: GWIJEMBQELNSSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  92.3
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• IONIC COMPOUND, COMPOSITION, CURED MATERIAL, HYDROGEL AND OPHTHALMIC LENS
  申请人：Satake Kohsuke

  公开号：US20130202551A1

  公开（公告）日：2013-08-08

  An ionic compound capable of providing a cured material having superior antibacterial property and oxygen permeability, and a composition containing the ionic compound, and a cured material, a hydro gel and an ophthalmic lens which have long-term sustainable antibacterial property and superior oxygen permeability. The ionic compound is represented by the following formula (1): In formula (1), P represents a polymerizable functional group. Q + represents a cationic group: Z represents an n-valent siloxanyl group in which the total atomic weight of a group of constituent atoms is no less than 70 and no greater than 1,000; X m− represents an m-valent anion; and n is an integer of 1 to 10, where provided that n is no less than 2, a plurality of P3 and Q + 3 are each independently as defined above.

  一种离子化合物，能够提供具有优越抗菌性能和氧透性的固化材料，以及含有该离子化合物的组合物，以及具有长期可持续抗菌性能和优越氧透性的固化材料、水凝胶和眼镜片。该离子化合物由以下式（1）表示： 在式（1）中，P代表可聚合的功能基团。Q + 代表阳离子基团：Z代表一个n价硅氧烷基团，其中构成原子的总原子量不小于70且不大于1,000；X m− 代表m价阴离子；n为1至10的整数，其中n不小于2时，多个P3和Q + 3分别独立定义如上所述。
• Ocular lens material
  申请人：Menicon Co., Ltd.

  公开号：EP0947856A2

  公开（公告）日：1999-10-06

  An ocular lens material comprising a polymer prepared by polymerizing a monomer mixture containing at least one of (A-1) a compound represented by the formula (I): wherein R1 is hydrogen atom or methyl group, R2 is an alkylene group having 1 to 8 carbon atoms, R3 is an alkyl group having 1 to 18 carbon atoms and X1 is a halogen atom, and (A-2) a compound represented by the formula (II): wherein R4 is hydrogen atom or methyl group, R5 is an alkylene group having 1 to 8 carbon atoms, R6 is an alkyl group having 1 to 18 carbon atoms and X2 is a halogen atom. The ocular lens material shows excellent antibacterial property.

  一种眼球晶状体材料，它包含一种聚合物，该聚合物是通过聚合一种单体混合物制备的，该单体混合物含有 (A-1) 至少一种由式(I)表示的化合物： 其中R1是氢原子或甲基，R2是具有1至8个碳原子的亚烷基，R3是具有1至18个碳原子的烷基，X1是卤素原子，和(A-2)式(II)代表的化合物： 其中 R4 为氢原子或甲基，R5 为具有 1 至 8 个碳原子的亚烷基，R6 为具有 1 至 18 个碳原子的烷基，X2 为卤素原子。这种眼球晶状体材料具有优异的抗菌性能。
• CONTACT LENS MATERIAL
  申请人：Menicon Co., Ltd.

  公开号：EP1696257A1

  公开（公告）日：2006-08-30

  A contact lens material which has high oxygen permeability and mechanical strength, and extremely small in an amount of remaining unpolymerized monomers, at the same time, low in a water absorption ratio and excellent in shape stability of a lens is provided. The contact lens material comprises a copolymer obtained by polymerizing copolymer components containing a particular silicone-containing monomer, wherein the total residual amount of unpolymerized monomer components remaining in the copolymer based on the copolymer is at most 3.5 % by weight, an oxygen permeability coefficient of the copolymer is at least 130 × 10-11 (cm2/sec)·(mLO2)/(mL·mmHg), and a water absorption ratio of the copolymer is at most 0.3 % by weight.

  一种隐形眼镜材料具有较高的透氧性和机械强度，剩余的未聚合单体量极少，同时吸水率低，镜片形状稳定性极佳。该隐形眼镜材料包括一种通过聚合含有特定含硅单体的共聚物成分而获得的共聚物，其中基于共聚物的未聚合单体成分的总残留量最多为 3.5%（按重量计），共聚物的透氧系数至少为 130 × 10-11 (cm2/sec)-(mLO2)/(mL-mmHg) ，共聚物的吸水率最多为 0.3%（按重量计）。
• IONIC COMPOUND, COMPOSITION, CURED PRODUCT, HYDROGEL, AND OCULAR LENS
  申请人：Menicon Co., Ltd.

  公开号：EP2581394A1

  公开（公告）日：2013-04-17

  An object of the invention is to provide an ionic compound capable of providing a cured material having superior antibacterial property and oxygen permeability, and a composition containing the ionic compound, and to provide a cured material, a hydrogel and an ophthalmic lens which have long-term sustainable antibacterial property and superior oxygen permeability. The present invention provides the ionic compound represented by the following formula (1): in the formula (1), P represents a polymerizable functional group. Q+ represents a cationic group; Z represents an n-valent siloxanyl group in which the total atomic weight of a group of constituent atoms is no less than 70 and no greater than 1,000; Xm- represents an m-valent anion; and n is an integer of 1 to 10, where provided that n is no less than 2, a plurality of Ps and Q+s are each independently as defined above.

  本发明的目的是提供一种能够提供具有优异抗菌性和透氧性的固化材料的离子化合物，以及一种含有该离子化合物的组合物，并提供一种具有长期持续抗菌性和优异透氧性的固化材料、水凝胶和眼科透镜。本发明提供了由下式（1）代表的离子化合物： 式（1）中，P 代表可聚合官能团。Q+ 代表阳离子基团；Z 代表正价硅氧烷基团，其中一组组成原子的总原子量不小于 70 且不大于 1,000；Xm- 代表 m 价阴离子；n 为 1 至 10 的整数，其中只要 n 不小于 2，多个 Ps 和 Q+ 就各自独立地如上所定义。
• POLYMER MATERIAL
  申请人：Menicon Co., Ltd.

  公开号：EP3822296A1

  公开（公告）日：2021-05-19

  The present invention provides a silicone-containing polymer material containing an internal wetting agent and being excellent in transparency, the silicone-containing polymer material being improved in antifouling property against lipids. The polymer material of the present invention is a polymer material, which is obtained by polymerizing a polymerizable mixture containing monomer components (a) and a hydrophilic polymer component (b), wherein the monomer components (a) include a silicone-containing monomer (a-1) having a siloxane bond and being free of any hydroxyl group, and a compatibilizing monomer (a-2) having a hydrogen bonding proton-containing group and being free of any silicon atom, and wherein the compatibilizing monomer has four or more carbon atoms, excluding carbon atoms contained in a polymerizable functional group, and has a solubility of less than 0.03 g/mL in water at 25°C.

  本发明提供了一种含硅聚合物材料，该材料含有内部润湿剂，透明度极佳，含硅聚合物材料对脂类的防污性能也有所改善。本发明的聚合物材料是通过聚合含有单体成分（a）和亲水性聚合物成分（b）的可聚合混合物而得到的聚合物材料，其中单体成分（a）包括具有硅氧烷键且不含任何羟基的含硅单体（a-1）、和具有含氢键质子基团且不含任何硅原子的相容单体 (a-2)，其中相容单体具有四个或更多的碳原子，不包括包含在可聚合官能团中的碳原子，并且在 25°C 时在水中的溶解度小于 0.03 g/mL。