methacrylic acid-(4-butyl-phenyl ester) | 92863-76-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: methacrylic acid-(4-butyl-phenyl ester)
• 英文别名: Methacrylsaeure-(4-butyl-phenylester)；Methacrylsaeure-<4-butyl-phenylester>；p-Butylphenyl methacrylate；(4-butylphenyl) 2-methylprop-2-enoate
• CAS: 92863-76-8
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.296
• InChiKey: VQWCARKIMUWGBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-丁基苯酚 、 甲基丙烯酰氯 生成 methacrylic acid-(4-butyl-phenyl ester)
  参考文献：
  名称：

  Scheremetewa et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959, p. 528,530, 531; engl. Ausg. S. 500, 502

  摘要：

  DOI：

文献信息

• New polymer materials for contact lens applications
  申请人：CIS Pharma AG

  公开号：US20200283560A1

  公开（公告）日：2020-09-10

  The present invention relates to copolymers made from a polymerization mixture comprising (a) one or more polymerizable monomers, which monomers are characterized as having at least one vinylic group and not containing an amino acid residue, (b) one or more not-functionalized side chain-linked amino acids, (c) one or more functionalized side chain-linked amino acids, (d) a free radical initiator and, optionally, (e) a chain-transfer-agent. It also relates to block copolymers comprising the same monomers. The invention also encompasses silicone hydrogel contact lenses coated with or comprising the latter copolymers and block copolymers as well methods for introducing the copolymers and block copolymers into silicone hydrogel contact lenses.

  本发明涉及由聚合混合物制成的共聚物，所述聚合混合物包括（a）一种或多种可聚合单体，该单体被表征为至少具有一个乙烯基团且不含氨基酸残基，（b）一种或多种未功能化的侧链连接的氨基酸，（c）一种或多种功能化的侧链连接的氨基酸，（d）自由基引发剂，以及可选地，（e）链转移剂。还涉及包含相同单体的嵌段共聚物。该发明还涵盖涂有或包含后述共聚物和嵌段共聚物的硅水凝胶隐形眼镜，以及将这些共聚物和嵌段共聚物引入硅水凝胶隐形眼镜的方法。
• Biocompatible polymers and co-polymers, and uses thereof
  申请人：Hitz Hans

  公开号：US20090232871A1

  公开（公告）日：2009-09-17

  The invention relates to highly biocompatible or biophilic un-cross-linked or cross-linked polymers comprising one or more side-chain active acrylic amino acids of formula I wherein: X is —NH(CH 2 ) 4 —, —O—C 6 H 4 —CH 2 —, —OCH 2 —, —O—CH(CH 3 )—, —S—CH 2 —, —O-proline, and R is H or CH 3 ; and wherein the polymer further includes a free radical initiator and, optionally, a cross-linking agent having a plurality of polymerizable ethylenically unsaturated groups. The invention further concerns various highly biocompatible, cross-linked co-polymers comprising one or more monomers of formula I, and one or more other polymerizable monomers. Uses of such polymers and co-polymers for the production of contact lenses, intraocular lenses, implants, wound healing slabs, additives for food and cosmetics, conductive plastics, spinnable fibers, and the like are disclosed.

  本发明涉及高生物相容性或亲生性的未交联或交联聚合物，其包括一个或多个侧链活性丙烯酸氨基酸（公式I），其中：X为—NH（CH2）4—，—O—C6H4—CH2—，—OCH2—，—O—CH（CH3）—，—S—CH2—，—O-脯氨酸，R为H或CH3；聚合物进一步包括自由基引发剂和可选的具有多个可聚合乙烯基不饱和基团的交联剂。本发明还涉及各种高生物相容性的交联共聚物，其中包括一个或多个公式I的单体和一个或多个其他可聚合单体。本发明还揭示了这些聚合物和共聚物的用途，用于生产隐形眼镜、人工晶体、植入物、伤口愈合垫、食品和化妆品添加剂、导电塑料、可旋转纤维等。
• Silicon compound and a production process for silicon compound
  申请人：Yamahiro Mikio

  公开号：US20070004932A1

  公开（公告）日：2007-01-04

  The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T 8 -silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material. A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R 1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A 2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R 1 group is the same as R 1 in formula (1), and A 1 is an organic functional group containing an acyloxy group.

  本发明的目的是提供一种新型的硅化合物，其具有酯型有机功能基，并提供一种使用所述硅化合物作为起始材料来提供具有羟基的T8-硅氧烷化合物的新方法。通过使用式（2）表示的硅化合物，通过生产过程获得式（1）表示的硅化合物。其中：在式（1）中，七个R1基团中的每一个独立地选择自氢、烷基、取代或未取代芳基和取代或未取代芳基烷基的群，A2是一个羟基端有机功能基，在式（2）中，每个R1基团与式（1）中的R1相同，A1是含有酰氧基的有机功能基。
• Novel resin composition, coating material comprising said resin composition and method for forming coatings
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0052330A1

  公开（公告）日：1982-05-26

  A resin composition comprising (A) a polymer having, in the molecule, at least two groups represented by the following structural formula (I): wherein R1 is isopropyl, sec-butyl, tert-butyl, a C2-20 alkyl group, a C3-20 cycloalkyl group, a C5-20 alkenyl group, a C3-20 hydroxyalkyl group, a C5-20 alkoxyalkyl group, a C3-20 aminoalkyl group, a C6-20 aryl group or a C6-20 arylalkyl group, and n is 0, 1 or 2, and (B) a polymer having an electron attractive group and an α,β-ethylenic double bond adjacent thereto. Though said composition is stable at room temperature, it is crosslinked and cured at high temperatures because the amino group of the polymer (A) adds to the double bond of the polymer (B). Accordingly, said resin composition is suitable for use as a cathodic electrocoating material.

  一种树脂组合物，包含(A)一种聚合物，其分子中至少有两个由以下结构式(I)代表的基团： 其中 R1 为异丙基、仲丁基、叔丁基、C2-20 烷基、C3-20 环烷基、C5-20 烯基、C3-20 羟烷基、C5-20 烷氧基烷基、C3-20 氨基烷基、C6-20 芳基或 C6-20 芳烷基，n 为 0、1 或 2；以及 (B) 具有引电子基团和邻接α,β-乙烯双键的聚合物。虽然所述组合物在室温下稳定，但由于聚合物（A）的氨基与聚合物（B）的双键相加，因此在高温下会发生交联和固化。因此，所述树脂组合物适合用作阴极电涂层材料。
• Biocompatible polymers and co-polymers comprising amino acids in the side chain
  申请人：Chemisches Institut Schaefer AG

  公开号：EP2292672A2

  公开（公告）日：2011-03-09

  The invention relates to highly biocompatible or biophilic un-cross-linked or cross-linked polymers comprising one or more side-chain active acrylic amino acids of formula I. The invention further concerns various highly biocompatible, cross-linked co-polymers comprising one or more monomers of formula I, and one or more other polymerizable monomers. Uses of such polymers and co-polymers for the production of contact lenses, intraocular lenses, implants, wound healing slabs, additives for food and cosmetics, conductive plastics, spinnable fibers, and the like are disclosed.

  本发明涉及高度生物相容性或亲生物性的未交联或交联聚合物，该聚合物包含一种或多种式 I 的侧链活性丙烯酸氨基酸。本发明还涉及由一种或多种式 I 单体和一种或多种其它可聚合单体组成的各种高生物相容性交联共聚物。本发明公开了此类聚合物和共聚物在生产隐形眼镜、眼内镜片、植入物、伤口愈合板、食品和化妆品添加剂、导电塑料、可纺纤维等方面的用途。