5-(2,6-diethyl-anilinomethyl)-4-methyl-2,4-dihydro-[1,2,4]triazole-3-thione | 72096-69-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(2,6-diethyl-anilinomethyl)-4-methyl-2,4-dihydro-[1,2,4]triazole-3-thione
• 英文别名: 3-[(2,6-diethylanilino)methyl]-4-methyl-1H-1,2,4-triazole-5-thione
• CAS: 72096-69-6
• 化学式: C₁₄H₂₀N₄S
• 分子量: 276.406
• InChiKey: PTWONSGZAXZWLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  71.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-(2,6-diethyl-anilinomethyl)-4-methyl-2,4-dihydro-[1,2,4]triazole-3-thione 生成 2,6-diethyl-N-(4-methyl-5-methylsulfanyl-4H-[1,2,4]triazol-3-ylmethyl)-aniline
  参考文献：
  名称：

  RIEBEL, H. -J.;EUE, L.;FAUST, W.

  摘要：

  DOI：
• 作为产物：
  描述：

  1-[[2-(2,6-diethylanilino)acetyl]amino]-3-methylthiourea 生成 5-(2,6-diethyl-anilinomethyl)-4-methyl-2,4-dihydro-[1,2,4]triazole-3-thione
  参考文献：
  名称：

  RIEBEL, H. -J.;EUE, L.;FAUST, W.

  摘要：

  DOI：

文献信息

• N-N-Bis(haloacyl)-diaza-cycloalkanes for protecting plants from
  申请人：Bayer Aktiengesellschaft

  公开号：US04392882A1

  公开（公告）日：1983-07-12

  The use of N,N'-bis-(haloacyl)-diaza-cycloalkanes of the general formula ##STR1## in which R.sup.1 represents alkyl or halogen, R.sup.2 represents halogen, R.sup.3 represents alkyl or halogen, R.sup.4 represents halogen, R.sup.5 represents hydrogen or alkyl with 1 to 4 carbon atoms, R.sup.6 represents hydrogen or alkyl with 1 to 4 carbon atoms and Q represents an alkylene chain which has 2 or 3 carbon atoms in the alkylene chain and is optionally monosubstituted or polysubstituted by alkyl with 1 to 4 carbon atoms, as antidotes for protecting crop plants from damage by herbicides.

  使用通式为##STR1##的N，N'-双(卤代酰基)-二氮杂环烷作为抗草甘膦剂保护作物免受草 herb 害的解毒剂，其中R1代表烷基或卤素，R2代表卤素，R3代表烷基或卤素，R4代表卤素，R5代表1至4个碳原子的氢或烷基，R6代表1至4个碳原子的氢或烷基，Q代表具有2或3个碳原子的烷基链，可单取代或多取代1至4个碳原子的烷基。
• Antidotes for protecting plants from herbicide damage
  申请人：Bayer Aktiengesellschaft

  公开号：US04422866A1

  公开（公告）日：1983-12-27

  The use of N,N'-disubstituted piperazines of the general formula ##STR1## in which R.sup.1 represents alkyl or halogen, R.sup.2 represents halogen and R.sup.3 represents phenyl (which optionally carries one or more substituents selected from alkyl, alkoxy, halogen, haloalkyl, nitro and alkanoyl), phenylalkyl which has 1 to 4 carbon atoms in the alkyl part (and which optionally carries one or more substituents on the phenyl part selected from alkyl, alkoxy, halogen, haloalkyl, nitro and alkanoyl), 3-phenyl-prop-2-enyl (which optionally carries one or more substituents on the phenyl part selected from alkyl, alkoxy, halogen, haloalkyl, nitro and alkanoyl), naphthyl (which optionally carries one or more substituents selected from alkyl, alkoxy, halogen, haloalkyl, nitro and alkanoyl), pyridyl (which optionally carries one or more substituents selected from alkyl, alkoxy, halogen, haloalkyl, nitro and alkanoyl), alkyl, formyl or alkoxycarbonyl, as antidotes for protecting crop plants from damage by herbicides.

  通式为##STR1##其中R.sup.1代表烷基或卤素，R.sup.2代表卤素，R.sup.3代表苯基（可选地携带一种或多种来自烷基、烷氧基、卤素、卤代烷基、硝基和烷酰基的取代基），苯基烷基（其烷基部分有1至4个碳原子，且可选地在苯基部分携带一种或多种来自烷基、烷氧基、卤素、卤代烷基、硝基和烷酰基的取代基），3-苯基丙-2-烯基（其可选地在苯基部分携带一种或多种来自烷基、烷氧基、卤素、卤代烷基、硝基和烷酰基的取代基），萘基（可选地携带一种或多种来自烷基、烷氧基、卤素、卤代烷基、硝基和烷酰基的取代基），吡啶基（可选地携带一种或多种来自烷基、烷氧基、卤素、卤代烷基、硝基和烷酰基的取代基），烷基、甲酰基或烷氧羰基，作为保护农作物免受除草剂损害的解毒剂。
• N-Azolylalkyl-anilines
  申请人：Bayer Aktiengesellschaft

  公开号：US04267338A1

  公开（公告）日：1981-05-12

  Novel N-azolylalkyl-aniline compound of the formula ##STR1## in which A is oxygen, sulfur or the radical >NR.sup.2, R is hydrogen or alkyl, R.sup.1 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, cycloalkyl, halogen, optionally substituted aryl, optionally substituted aralkyl or the radicals --OR.sup.3, --SR.sup.3 or --NH.sup.2 R.sup.3, R.sup.2 is hydrogen, alkyl or optionally substituted aryl, R.sup.3 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, cycloalkyl or optionally substituted aralkyl, X is alkyl, Y is alkyl or halogen and n is 0, 1 or 2.

  化合物的结构式为##STR1##其中A为氧、硫或基团>NR.sup.2，R为氢或烷基，R.sup.1为氢、烷基、卤代烷基、烯基、炔基、环烷基、卤素、可选取代芳基、可选取代芳基烷基或基团--OR.sup.3、--SR.sup.3或--NH.sup.2 R.sup.3，R.sup.2为氢、烷基或可选取代芳基，R.sup.3为氢、烷基、卤代烷基、烯基、炔基、环烷基或可选取代芳基烷基，X为烷基，Y为烷基或卤素，n为0、1或2。
• N-Acyl-piperidone ketal compounds and their use as antidotes for
  申请人：Bayer Aktiengesellschaft

  公开号：US04548639A1

  公开（公告）日：1985-10-22

  N-Acyl-piperidone ketal compounds of the formula ##STR1## in which R.sup.1 represents alkyl or halogen, R.sup.2 represents halogen, R.sup.3 represents alkyl and R.sup.4 represents alkyl, or R.sup.3 and R.sup.4 together represent an optionally branched alkylene chain, and R.sup.5, R.sup.6, R.sup.7 and R.sup.8 independently of one another represent hydrogen or alkyl, and their use as antidotes for protecting crop plants from herbicidal damage.

  公式为##STR1##的N-Acyl-piperidone ketal化合物中，其中R.sup.1代表烷基或卤素，R.sup.2代表卤素，R.sup.3代表烷基，R.sup.4代表烷基或R.sup.3和R.sup.4一起代表一个可选的支链烷基链，而R.sup.5，R.sup.6，R.sup.7和R.sup.8独立地代表氢或烷基，并且它们用作保护作物免受除草剂损伤的解毒剂。
• Compositions and methods for improving the tolerance by crop plants of
  申请人：Bayer Aktiengesellschaft

  公开号：US04312664A1

  公开（公告）日：1982-01-26

  Novel herbicidal composition comprising (1) a herbicidally active acetanilide and (2) as an antidote against damage to crop plants, N,N-diallyl-dichloroacetamide of the formula ##STR1##

  新型除草剂组合物，包括(1)具有除草活性的乙酰苯胺和(2)作为对抗对作物植物的损害的解毒剂，化学式为N,N-二烯丙基-二氯乙酰胺。