Pd(bis(phenylthio)methane)2Cl2 | 159574-56-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Pd(bis(phenylthio)methane)2Cl2
• 英文别名: trans-[Pd(PhSCH2SPh)2Cl2]；trans-PdCl2L(2)2；dichloropalladium;phenylsulfanylmethylsulfanylbenzene
• CAS: 159574-56-8
• 化学式: C₂₆H₂₄Cl₂PdS₄
• 分子量: 642.067
• InChiKey: RQQCZSJVSLEIIF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium tetrachloropalladate(II) 、 Pd(bis(phenylthio)methane)2Cl2 以 not given 为溶剂， 生成 [(Pd(PhSCH2SPh)Cl2)n]
  参考文献：
  名称：

  Palladium(II) and platinum(II) complexes of bis(phenylthio)methane and bis(methylthio)methane

  摘要：

  DOI：

  10.1016/s0020-1693(00)88337-1
• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 双(苯硫基)甲烷 以 乙醇 为溶剂， 以81%的产率得到Pd(bis(phenylthio)methane)2Cl2
  参考文献：
  名称：

  Synthesis and spectroscopic studies of palladium and platinum complexes of methylene-backboned dithio-, diseleno- and ditelluro-ether ligands, RECH2ER (R = Me or Ph; E = S, Se or Te)

  摘要：

  The complexes [ML2Cl2] (M = Pd or Pt; L = PhSCH2SPh, MeSCHSMe, PhSeCH2SePh or MeSeCH2SeMe), which are square planar with monodentate sulfur or selenium ligands, have been prepared. In the solid state, on the basis of IR and Raman data, the palladium complexes are trans and the platinum cis, whilst in solution multinuclear NMR spectroscopy (H-1, Pt-195-{H-1}, and Se-77-{H-1}) reveal that both cis and trans isomers and meso and DL enantiomers are present, the isomer populations varying with L and M in a systematic way. The complexes [MLCl2] are stable in solution for L = PhSCH2SPh, but the other complexes lose L to precipitate polymeric [(MLCl2)n] complexes. The ditelluroethers, MeTeCH2TeMe and PhTeCH2TePh, form only the latter type of complex. The crystal structure of trans-[Pd(PhSCH2SPh)2Cl2] has been determined and contains a trans square-planar palladium atom with one co-ordinated and one free sulfur atom associated with each dithioether ligand [Pd-Cl 2.292(l) and Pd-S 2.329(l) angstrom].

  DOI：

  10.1039/dt9940002835

文献信息

• Potapov; Khisamutdinov; Murinov, Russian Journal of Inorganic Chemistry, 1999, vol. 44, # 3, p. 371 - 375
  作者：Potapov、Khisamutdinov、Murinov、Baikova、Puzin

  DOI：——

  日期：——