silver (acetylacetonato) triphenylphosphane | 28015-66-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: silver (acetylacetonato) triphenylphosphane
• 英文别名: Ag(acetylacetonate)(P(C6H5)3)；Ag(acac)(PPh3)
• CAS: 28015-66-9；27290-66-0
• 化学式: C₂₃H₂₂AgO₂P
• 分子量: 469.268
• InChiKey: YVYSPWIQVTUSNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  silver (acetylacetonato) triphenylphosphane 、 tris(diphenylphosphinothioyl)methane 以 二氯甲烷 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  Concepcion Gimeno; Jones, Peter G.; Laguna, Antonio, Chemische Berichte, 1996, vol. 129, # 5, p. 585 - 588

  摘要：

  DOI：
• 作为产物：
  描述：

  Silver, bromobis(triphenylphosphine)- 以 氯仿 、 苯 为溶剂， 生成 silver (acetylacetonato) triphenylphosphane
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B7, 1.23.3, page 208 - 220

  摘要：

  DOI：

文献信息

• Gold and Silver Complexes with the Ligands <i>N</i> ‐[Bis(isopropoxy)thiophosphoryl]thiobenzamide and <i>N</i> ‐[Bis(isopropoxy)thiophosphoryl] <i>N</i> ′‐phenylthiourea
  作者：Olga Crespo、Vasiliy V. Brusko、M. Concepción Gimeno、M. Loreto Tornil、Antonio Laguna、Nail G. Zabirov

  DOI：10.1002/ejic.200300328

  日期：2004.1

  Gold and silver complexes with the N-[bis(isopropoxy)thiophosphoryl]thiobenzamide (HL1) and N-[bis(isopropoxy)thiophosphoryl]-N′-phenylthiourea (HL2) ligands are reported. The compounds [M(HL)(PPh3)]TfO, [Ag(HL)(TfO)] and [Ag(HL)(PPh3)2]TfO were obtained by the reaction of both ligands with the corresponding trifluoromethanesulfonate salts. The (acetylacetonato)gold and -silver materials [M(acac)(PPh3)]

  据报道，金和银与 N-[双（异丙氧基）硫代磷酰基]硫代苯甲酰胺（HL1）和 N-[双（异丙氧基）硫代磷酰基]-N'-苯基硫脲（HL2）配体形成络合物。化合物[M(HL)(PPh3)]TfO、[Ag(HL)(TfO)]和[Ag(HL)(PPh3)2]TfO是通过两种配体与相应的三氟甲磺酸盐反应获得的。（乙酰丙酮）金和银材料 [M(acac)(PPh3)] 或 [Au(acac)(C6F5)2] 导致配体去质子化并提供 [ML(PPh3)] 或 [AuL( )2] ，而 [Au(TfO)(PPh3)] 与 HL1 在 KOH/MeOH 中以 2:1 的摩尔比反应得到 [Au2(L1)(PPh3)2]TfO。还报道了第一个均质阴离子金属化合物 [AuIL2]-。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
• Reactivity of an Acetylenephosphino Gold(III) Precursor:  Addition to the Triple Bond or Formation of Alkynyl Derivatives
  作者：Manuel Bardají、Antonio Laguna、Peter G. Jones

  DOI：10.1021/om010385+

  日期：2001.9.1

  We have synthesized the gold(III) complex Au(C6F5)3(PPh2CCH) (1), containing an acetylene moiety. Reactions with sodium alkoxides lead chemoselectively and regioselectively to gold(III) complexes containing the new ligand (2-alkoxyethenyl)diphenylphosphine or (2,2-dialkoxyethyl)diphenylphosphine, via a single or double alcohol addition to the acetylenephosphine fragment. Reaction of complex 1 with

  我们已经合成了含有乙炔部分的金（III）络合物Au（C 6 F 5）3（PPh 2 CCH）（1）。与醇钠的反应通过对乙炔膦片段的单或双醇加成，化学上和区域上选择性地导致了含有新的配体（2-烷氧基乙烯基）二苯基膦或（2,2-二烷氧基乙基）二苯基膦的金（III）配合物。配合物1与乙酰丙酮金（I）或银（I）衍生物的反应得到二，三或四核炔基膦基配合物，即Au III（C 6 F 5）3（PPh 2 CC）M I（PPh 3）（M = Au，Ag），Au III（C 6 F 5）3（PPh 2 CC）} 2 Au I和Au III（C 6 F 5）3（PPh 2 CC）Au I } 2（μ-PPH 2 CH 2 CH 2 PPH 2）。Au（C 6 F 5）3（PPh 2 CH 2 CH（OMe）2）和Au III（C通过X射线衍射研究确定了6 F 5）3（PPh 2 CC）Au I（PPh
• Metal β-diketone complexes. Part VI. Some β-diketone complexes of copper(<scp>I</scp>), silver(<scp>I</scp>), and gold(<scp>I</scp>)
  作者：D. Gibson、B. F. G. Johnson、J. Lewis

  DOI：10.1039/j19700000367

  日期：——

  Two classes of β-diketone complexes of CuI, AgI, and AuI have been prepared viz.: class (i) L2M(β-diketone), M = Cu, L = Ph3P, β-diketone = conjugate base of acetylacetone (acac), benzoylacetone (ba), trifluoro-acetylacetone (tfa), or hexafluoroacetylacetone (hfa), and M = Ag, L = Ph3P, β-diketone = ba or hfa; and class (2) LM(β-diketone), M = Ag, L = Ph3P, β-diketone = acac or tfa, and M = Au, L =

  已经制备了两类Cu I，Ag I和Au I的β-二酮配合物。：（i）类L 2 M（β-二酮），M = Cu，L = Ph 3 P，β-二酮=乙酰丙酮（acac），苯甲酰基丙酮（ba），三氟乙酰丙酮（tfa）或六氟乙酰丙酮的共轭碱（hfa），M = Ag，L = Ph 3 P，β-二酮= ba或hfa；和（2）类LM（β-二酮），M = Ag，L = Ph 3 P，β-二酮= acac或tfa，M = Au，L = Ph 3 P，Ph 2 EtP，Et 3 P，（ Ph·Me）3 P或Ph 3As，β-二酮= acac或ba。根据分子量数据以及ir和nmr光谱研究，表明Cu I和Ag I的配合物包含氧键合的β-二酮，无论其成分如何，而Au I的配合物在所有情况下均包含碳键合的配体。案件。讨论了这些观察结果的立体化学后果。
• Fernandez, Eduardo J.; Gimeno, M. Concepcion; Jones, Peter G., Chemische Berichte, 1995, vol. 128, # 2, p. 121 - 124
  作者：Fernandez, Eduardo J.、Gimeno, M. Concepcion、Jones, Peter G.、Laguna, Antonio、Laguna, Mariano、et al.

  DOI：——

  日期：——
• Synthesis and structural characterization of methanide silver(<scp>I</scp>) complexes. Unprecedented co-ordination of the methanide ligand in [Ag₂(PPh₃)₂(SPPh₂CHPPh₂CHCO₂Me)]ClO₄·4CH₂Cl₂
  作者：Maria Concepción Gimeno、Peter G. Jones、Antonio Laguna、Maria Dolores Villacampa

  DOI：10.1039/dt9950000805

  日期：——

  The mixed phosphine-phosphonium salt [PPh(2)CH(2)PPh(2)CH(2)CO(2)Me]ClO4 reacts with [Ag(acac)(PPh(3))] (acac = acetylacetonate), with deprotonation of the ligand, displacing acac as acetylacetone and yielding the complex [Ag(OClO3)(PPh(3))(PPh(2)CH(2)PPh(2)CHCO(2)Me)], where the methanide ligand chelates the four-co-ordinate metal centre. The sulfide or oxide derivatives [XPPh(2)CH(2)PPh(2)R]ClO4 (X = S or O; R = Me or CH(2)CO(2)Me) also react with [Ag(acac)(PPh(3))] in various stoichiometries to give [Ag(PPh(3))(XPPh(2)CHPPh(2)Me)]ClO4 or [Ag-2(PPh(3))(2)(XPPh(2)CHPPh(2)CHCO(2)Me)]ClO4; in the latter the methanide ligand co-ordinates both silver atoms through four donor centres (X, C, C, CO). Two of these derivatives have been characterized by X-ray analysis: [Ag(OClO3)(PPh(3))(PPh(2)CH(2)PPh(2)CHCO(2)Me)] crystallizes in the monoclinic space group P2(1)/n, a = 12.448(4); b = 21.021(7), c = 19.803(7) Angstrom, beta = 108.60(3)degrees, Z = 4, T = -100 degrees C; [Ag-2(PPh(3))(2)(SPPh(2)CHPPh(2)CHCO(2)Me)]ClO4 crystallizes in the same space group with a = 13.759(3), b = 12.074(3), c = 43.353(9) Angstrom, beta = 92.62(2)degrees, Z = 4, T = -1000 degrees C.