1-(1H-inden-3'-yl)oct-7-en-2-ol | 1398566-07-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(1H-inden-3'-yl)oct-7-en-2-ol
• CAS: 1398566-07-8
• 化学式: C₁₇H₂₂O
• 分子量: 242.361
• InChiKey: KBTCGJHCZMQFOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.12
• 重原子数：
  18.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  1-(1H-inden-3'-yl)oct-7-en-2-ol 在 咪唑 、 碘 、 三苯基膦 作用下， 以 乙醚 、 乙腈 为溶剂， 反应 0.33h， 以93.8%的产率得到
  参考文献：
  名称：

  Immobilization of ethylene bis-indenyl ligands on functionalized silica gel

  摘要：

  Four ethylene bis-indenyl ligands containing tethers of various lengths were successfully immobilized on the surface of functionalized silica gel. The strategy of immobilization was based on catalytic thiol-ene coupling of terminal alkene groups in the tethers with surface thiol groups. Obtained materials have high BET surface area and pore volume. The method developed can be used for immobilization of catalytically active bis-indenyl metallocene complexes, thus preventing their dimerization and deactivation. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.07.089
• 作为产物：
  描述：

  1,2-环氧-7-辛烯 、 茚 在 正丁基锂 、 copper(l) iodide 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 以24.2%的产率得到1-(1H-inden-3'-yl)oct-7-en-2-ol
  参考文献：
  名称：

  Immobilization of ethylene bis-indenyl ligands on functionalized silica gel

  摘要：

  Four ethylene bis-indenyl ligands containing tethers of various lengths were successfully immobilized on the surface of functionalized silica gel. The strategy of immobilization was based on catalytic thiol-ene coupling of terminal alkene groups in the tethers with surface thiol groups. Obtained materials have high BET surface area and pore volume. The method developed can be used for immobilization of catalytically active bis-indenyl metallocene complexes, thus preventing their dimerization and deactivation. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.07.089