| 145051-59-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 145051-59-8
• 化学式: C₁₈H₂₄N₄
• 分子量: 296.415
• InChiKey: XSPHEZZYBANGOB-GOSISDBHSA-N

反应信息

• 作为反应物：
  描述：

  manganese(II) triflate 、 以 not given 为溶剂， 生成 Λ-α-(S)-N-methyl(pyridin-2-yl)-N-((1-(pyridin-2-ylmethyl)pyrrolidin-2-yl)methyl)methanamine manganese(II) bis(trifluoromethanesulfonate)
  参考文献：
  名称：

  Non-heme manganese complexes of C1-symmetric N4 ligands: Synthesis, characterization and asymmetric epoxidations of α,β-enones

  摘要：

  A series of proline-derived C-1-symmetric chiral tetradentate N ligands and their manganese complexes have been synthesized and characterized. Their applications in enantioselective epoxidations of alpha,beta-enones were explored reaching good yields and up to 71% ee at room temperature. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.03.034