4,9-Dihydro-1,3-dimethyl-4,9-o-benzenonaphtho<2,3-c>thiophen | 34085-18-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4,9-Dihydro-1,3-dimethyl-4,9-o-benzenonaphtho<2,3-c>thiophen
• 英文别名: 16,18-Dimethyl-17-thiapentacyclo[6.6.5.02,7.09,14.015,19]nonadeca-2,4,6,9,11,13,15,18-octaene
• CAS: 34085-18-2
• 化学式: C₂₀H₁₆S
• 分子量: 288.413
• InChiKey: GTCJRIFROUTIFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Emissive polymers and devices incorporating these polymers
  申请人：Swager M. Timothy

  公开号：US20070081921A1

  公开（公告）日：2007-04-12

  The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics such as heterocycles, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

  本发明涉及一类具有色团的发光和导电聚合物组合物，特别是这些组合物的固态薄膜表现出增加的发光寿命、量子产率和放大的发射。这些理想的特性可以通过设计刚性基团的聚合物来提供，以防止聚合物在固化时重新组织、聚集或π-堆积。这些聚合物还可以表现出与溶剂和热暴露相比异常高的稳定性。本发明还涉及一种通过这些聚合物的发光和导电特性来感知分析物的传感器和方法。通过在聚合物表面激活色团来感知分析物。分析物包括芳香族化合物，如杂环化合物、磷酸酯基团，特别是气态炸药和化学战剂。本发明还涉及通过将具有能量迁移途径的聚合物纳入或将聚合物作为块共聚物或多层来放大发射的装置和方法。
• EMISSIVE POLYMERS AND DEVICES INCORPORATING THESE POLYMERS
  申请人：Swager Timothy M.

  公开号：US20110175035A1

  公开（公告）日：2011-07-21

  The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

  本发明涉及一类具有色团的发光和导电聚合物组合物，特别是这些组合物的固体薄膜表现出增强的发光寿命、量子产率和放大的发射。这些理想的性质可以通过具有刚性基团的聚合物来实现，以防止聚合物在固化时重新组织、聚集或π-堆积。这些聚合物还可以表现出与溶剂和热暴露相关的非常高的稳定性。本发明还涉及一种传感器和一种通过这些聚合物的发光和导电性能来感测分析物的方法。通过激活聚合物表面的色团来感测分析物。分析物包括芳香族化合物、磷酸酯基团和特别是气态炸药和化学战剂。本发明还涉及通过将具有能量迁移途径的聚合物纳入到块共聚物或多层中来放大发射的装置和方法。
• US7208122B2
  申请人：——

  公开号：US7208122B2

  公开（公告）日：2007-04-24
• US7943062B2
  申请人：——

  公开号：US7943062B2

  公开（公告）日：2011-05-17
• US8198096B2
  申请人：——

  公开号：US8198096B2

  公开（公告）日：2012-06-12