Hydron;2-hydroxy-6-(phenyliminomethyl)phenolate | 141281-43-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: Hydron;2-hydroxy-6-(phenyliminomethyl)phenolate
• 英文别名: hydron;2-hydroxy-6-(phenyliminomethyl)phenolate
• CAS: 141281-43-8
• 化学式: C₁₃H₁₁NO₂
• 分子量: 213.236
• InChiKey: IKCNVDHSEBASIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.8
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 海关编码：
  2925290090

反应信息

• 作为反应物：
  描述：

  Hydron;2-hydroxy-6-(phenyliminomethyl)phenolate 在 氢气 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 反应 18.0h， 以94%的产率得到(anilinomethyl)catechol
  参考文献：
  名称：

  室温和 H2 大气压下用可重复使用的双金属 PdCo-Fe3O4 催化剂还原亚胺

  摘要：

  由于过渡金属之间的协同作用，双金属纳米催化剂已被用于发展有机反应。报道了在 PdCo-Fe 3 O 4纳米粒子存在下，在大气压和室温下，用 H 2还原亚胺来合成胺的新方法。简单的过程、温和的反应条件、高周转数和可回收性将该反应的范围扩展到实际应用。

  DOI：

  10.1039/d1ra08552b

文献信息

• Ruthenium(II) Complexes of O,N-donor Schiff base ligands and their use as catalytic organic oxidants
  作者：Ahmed M. El-Hendawy、Abdulla H. Alkubaisi、Abd El-Ghany El-Kourashy、Mai M. Shanab

  DOI：10.1016/s0277-5387(00)83051-x

  日期：1993.10

  A number of new ruthenium(II) complexes, [Ru(PPh3)2L2] (L = monoanions of Schiff bases formed from 2,3-dihydroxybenzaldehyde, 3,5-dibromosalicylaldehyde and salicylaldehyde with aniline or its p-substituents), have been prepared. They were characterized by spectroscopic techniques and investigated by cyclic voltammetry. The effective catalytic oxidation of alcohols by these complexes in the presence of N-methylmorpholine-N-oxide or molecular oxygen gas as co-oxidants is reported.
• Schiff base complexes of ruthenium(III), molybdenum(VI) and uranium(VI), and use of the former as catalytic organic oxidants
  作者：Ahmed M. El-Hendawy、Abd El-Ghany El-Kourashy、Mai M. Shanab

  DOI：10.1016/s0277-5387(00)83299-4

  日期：1992.1

  The new complexes [RuIIIX2(AsPh3)2(HL)] (X = Cl, Br; HL = monoanions of Schiff bases formed from condensation of 2,3-dihydroxybenzaldehyde and aniline or its omicron- and p-substituted derivatives), cis-[MoO2(HL)2] and trans-[UO2(HL)2.nH2O] (n = 0 or 2) have been isolated. They were characterized by spectroscopic techniques and investigated by cyclic voltammetry. The ruthenium(III) complexes were found to be effective catalysts for oxidation of primary alcohols to aldehydes, secondary alcohols to ketones and 3,5-di(tert-butyl)catechol to the corresponding omicron-benzoquinone in the presence of N-methyl-morpholine-N-oxide as co-oxidant.
• Reduction of imines with a reusable bimetallic PdCo–Fe₃O₄ catalyst at room temperature under atmospheric pressure of H₂
  作者：Sabyuk Yang、Byeong Moon Kim

  DOI：10.1039/d1ra08552b

  日期：——

  the development of organic reactions, owing to the synergistic effect between the transition metals. A new procedure for synthesizing amines by the reduction of imines with H2 at atmospheric pressure and room temperature in the presence of PdCo–Fe3O4 nanoparticles is reported. The straightforward procedure, mild reaction conditions, high turnover number, and recyclability extend the scope of this reaction

  由于过渡金属之间的协同作用，双金属纳米催化剂已被用于发展有机反应。报道了在 PdCo-Fe 3 O 4纳米粒子存在下，在大气压和室温下，用 H 2还原亚胺来合成胺的新方法。简单的过程、温和的反应条件、高周转数和可回收性将该反应的范围扩展到实际应用。