triphenyl (non-3-yn-1-yl)phosphonium bromide | 31545-66-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenyl (non-3-yn-1-yl)phosphonium bromide
• 英文别名: -triphenyl-phosphonium-bromid；Non-3-inyltriphenylphosphonium-bromid
• CAS: 31545-66-1
• 化学式: Br*C₂₇H₃₀P
• 分子量: 465.413
• InChiKey: QHCLTCBKUOQSIH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.96
• 重原子数：
  29.0
• 可旋转键数：
  8.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  triphenyl (non-3-yn-1-yl)phosphonium bromide 生成
  参考文献：
  名称：

  The synthesis of a leukotriene with SRS-like activity

  摘要：

  DOI：

  10.1016/s0040-4039(00)92753-9
• 作为产物：
  描述：

  3-壬炔-1-醇 在 N-溴代丁二酰亚胺(NBS) 、 三苯基膦 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 生成 triphenyl (non-3-yn-1-yl)phosphonium bromide
  参考文献：
  名称：

  Stereochemistry of the microbial generation of .delta.-decanolide, .gamma.-dodecanolide, and .gamma.-nonanolide from C18 13-hydroxy, C18 10-hydroxy, and C19 14-hydroxy unsaturated fatty acids

  摘要：

  (S)-delta-Decanolide (4) was isolated from cultures of Cladosporium suaveolens after the microorganism was fed either (S)- or (R,S)-coriolic acid (1). Feeding (R,S)-10-hydroxyoctadec-(8E)-enoic acid (2) to Yarrowia lipolytica produced (S)-gamma-dodecanolide. When (S)-homocoriolic acid (3) was fed to C.suaveolens, gamma-nonalide slightly enriched in the S enantiomer was produced. At some stage in the biodegradation of 3, an inversion of configuration, from S to R, occurred and was accompanied by the loss of the hydrogen atom originally present on C-14, as GLC/MS analysis of the products of feeding C. suaveolens with dideuterated 10 showed.

  DOI：

  10.1021/jo00018a001

文献信息

• Synthesis of the sulfones of leukotriene C4, D4, and E4
  作者：Yves Girard、Marie Larue、Thomas R. Jones、Joshua Rokach

  DOI：10.1016/s0040-4039(00)87012-4

  日期：1982.1

  A simple one-step preparation of the sulfones of Leukotriene C4, D4 and E4 has been developed by the direct oxidation of the parent compounds. An alternative synthesis of these sulfones has also been carried out by reduction of an acetylenic precursor.

  通过母体化合物的直接氧化，已经开发出一种简单的一步法制备白三烯C 4，D 4和E 4的砜。还通过还原炔属前体来进行这些砜的替代合成。
• Lellouche, J. P.; Gigou-Barbedette, A.; Gree, R., Bulletin de la Societe Chimique de France, 1992, vol. 129, p. 605 - 624
  作者：Lellouche, J. P.、Gigou-Barbedette, A.、Gree, R.

  DOI：——

  日期：——