(4-Methoxy-benzyl)-((E)-7-trimethylsilanyl-1-trimethylsilanyloxy-hept-5-enyl)-carbamic acid benzyl ester | 840530-64-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Methoxy-benzyl)-((E)-7-trimethylsilanyl-1-trimethylsilanyloxy-hept-5-enyl)-carbamic acid benzyl ester
• CAS: 840530-64-5
• 化学式: C₂₉H₄₅NO₄Si₂
• 分子量: 527.852
• InChiKey: ZSVOCAFMYQADAX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (4-Methoxy-benzyl)-((E)-7-trimethylsilanyl-1-trimethylsilanyloxy-hept-5-enyl)-carbamic acid benzyl ester 在 碘 、 四氯化锡 作用下， 以 二氯甲烷 为溶剂， 生成 (4aR,7aR)-4-Iodomethyl-1-(4-methoxy-benzyl)-hexahydro-cyclopenta[d][1,3]oxazin-2-one
  参考文献：
  名称：

  A new entry to functionalized cycloalkylamines: diastereoselective intramolecular amidoalkylation of N,O-acetal TMS ether possessing allylsilane

  摘要：

  Highly diastereoselective cyclization (>20:1) as a new entry to functionalized cycloalkylamines has been conducted with acyclic N,O-acetal TMS ethers possessing an allylsilane moiety. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.136
• 作为产物：
  描述：

  Hex-5-enoyl-(4-methoxy-benzyl)-carbamic acid benzyl ester 在 Grubbs catalyst first generation 二异丁基氢化铝 作用下， 以 二氯甲烷 为溶剂， 生成 (4-Methoxy-benzyl)-((E)-7-trimethylsilanyl-1-trimethylsilanyloxy-hept-5-enyl)-carbamic acid benzyl ester
  参考文献：
  名称：

  A new entry to functionalized cycloalkylamines: diastereoselective intramolecular amidoalkylation of N,O-acetal TMS ether possessing allylsilane

  摘要：

  Highly diastereoselective cyclization (>20:1) as a new entry to functionalized cycloalkylamines has been conducted with acyclic N,O-acetal TMS ethers possessing an allylsilane moiety. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.136