4-Hydroxy-benzylsulfonsaeure | 10536-35-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-Hydroxy-benzylsulfonsaeure
• 英文别名: (4-hydroxy-phenyl)-methanesulfonic acid；(4-Hydroxy-phenyl)-methansulfonsaeure；(4-Hydroxyphenyl)methanesulfonic acid
• CAS: 10536-35-3
• 化学式: C₇H₈O₄S
• 分子量: 188.204
• InChiKey: VRYLXDRQGIZWOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  83
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-Hydroxy-benzylsulfonsaeure 、 间苯三酚 生成 2-[(4-Hydroxyphenyl)methyl]benzene-1,3,5-triol
  参考文献：
  名称：

  MCGRAW, GERALD W.;LAKS, PETER E.;HEMINGWAY, RICHARD W., J. WOOD CHEM. AND TECHNOL., 8,(1988) N 1, 91-109

  摘要：

  DOI：
• 作为产物：
  描述：

  对羟基苯甲醇 在 水 、 sodium sulfite 作用下， 生成 4-Hydroxy-benzylsulfonsaeure
  参考文献：
  名称：

  p-Hydroxy-Benzyl Ethers As Lignin Models. II

  摘要：

  DOI：

  10.1246/bcsj.27.53

文献信息

• Modified oriented polyacetal product
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0317107A2

  公开（公告）日：1989-05-24

  There is disclosed a modified oriented polyacetal product in which the surface of the product is coated partly or entirely with a phenolic compound-polyacetal composite layer which improves the affinity of the surface towards dissimilar materials. Also disclosed is a process for forming the surface which comprises heating the surface in contact with the phenolic compound and optionally a resorcinol-formaldehyde condensation product. The modified oriented polyacetal product is useful for the preparation of composite materials.

  本发明公开了一种改性拉伸聚缩醛产品，该产品的表面部分或全部涂有一层酚醛复合物-聚缩醛复合层，可提高表面对异种材料的亲和力。此外，还公开了一种形成表面的工艺，包括加热与酚类化合物和间苯二酚-甲醛缩合产物接触的表面。改性定向聚缩醛产品可用于制备复合材料。
• Monoazo red reactive dye compound of vinylsulfone type
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0372543A1

  公开（公告）日：1990-06-13

  A monoazo compound represented by the general formula I (in the free acid form), wherein D is unsubstituted or substituted phenylene or naphthylene, X is unsubstituted or substituted pyridinio, Z is -SO₂CH=CH₂ or -SO₂CH₂CH₂L inwhich L is a group capable of being split by the action of an alkali, and Y is -V-R in which V is -O- or -S-, and R is hydrogen or unsubstituted or substituted alkyl, cyclohexyl, phenyl, naphthyl or benzyl, or in which R₁ and R₂ independently of one another are each hydrogen or unsubstituted or substituted alkyl, phenyl, naphthyl or benzyl, which is superior in solubility and useful for dyeing or printing fiber materials such as cellulose in a red color with superior build-up property.

  由通式 I（游离酸形式）代表的单偶氮化合物、 其中 D 是未取代或取代的亚苯基或亚萘基，X 是未取代或取代的吡啶基，Z 是 -SO₂CH=CH₂ 或 -SO₂CH₂CH₂L ，其中 L 是能在碱作用下分裂的基团、Y 是-V-R，其中 V 是-O-或-S-，R 是氢或未取代或取代的烷基、环己基、苯基、萘基或苄基，或 其中 R₁ 和 R₂ 各自独立地为氢或未取代或取代的烷基、苯基、萘基或苄基，其溶解性更佳，可用于纤维素等纤维材料的红色染色或印花，并具有更佳的上染性能。
• Ink compositions for ink jet recording
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0481449A2

  公开（公告）日：1992-04-22

  An ink composition for ink jet recording, which contains a water-soluble dye, an organic solvent and water, in which the dye is represented by the formula (1) as shown in the state of free acid:         D - (SO₂CH₂CH₂SO₃H)m   (1) wherein D represents a dye residue selected from the group of monoazo and polyazo dyes, their complexes with Cr, Fe, Co and Cu, copper and nickel phthalocyanine dyes, anthraquinone dyes, dioxazine dyes, and formazane complex dyes, and m represents an integer of 1, 2, 3 or 4, and which is superior in its stability during preservation and while being used, thermal stability, image clearness, water resistivity, light fastness, etc.

  一种用于喷墨记录的墨水组合物，它含有一种水溶性染料、一种有机溶剂和水，其中染料由式（1）表示，如游离酸状态所示： D - (SO₂CH₂CH₂SO₃H)m (1) 其中 D 代表一种染料残留物，选自单偶氮和多偶氮染料、它们与 Cr、Fe、Co 和 Cu 的络合物、铜和镍酞菁染料、蒽醌染料、二噁嗪染料和甲臢嗪络合物染料，m 代表 1、2、3 或 4 的整数，并且在保存和使用过程中的稳定性、热稳定性、图像清晰度、耐水性、耐光牢度等方面更优越。
• Disazo compounds and use thereof as fiber reactive dyes
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0609832A1

  公开（公告）日：1994-08-10

  A bisazo compound of the following formula: wherein R¹ and R³ are each hydrogen or alkyl; D is phenylene or naphthylene; one of X¹ and X² is NH₂ and the other is OH; Z¹ and Z² are each -CH=CH₂ or -CH=CH₂Z' in which Z' is a splittable group; B is monosulfophenylene, monosulfophenylene-methylene or mono- or disulfonaphthylene-methylene; U is phenylene or an aliphatic bridging group; and J is an amono-derivative group or, J may be alkoxy when X¹ is OH and U is phenylene, and J may be alkoxy or phenoxy when X¹ is OH and U is the aliphatic bridging group. This compound is useful for dyeing or printing fiber materials and gives a dyed or printed product having a color superior in various fastness properties with superior build-up property.

  下式所示的双偶氮化合物： 其中 R¹ 和 R³ 分别为氢或烷基；D 为亚苯基或萘基；X¹ 和 X² 中的一个为 NH₂，另一个为 OH；Z¹ 和 Z² 分别为 -CH=CH₂ 或 -CH=CH₂Z'，其中 Z' 为可拆分基团；B 为单亚磺酰亚苯基、单亚磺酰亚苯基或单亚磺酰亚苯基或二亚磺酰亚萘基；U 是亚苯基或脂肪族桥基；J 是氨基衍生物基团，或者，当 X¹ 是 OH 和 U 是亚苯基时，J 可以是烷氧基；当 X¹ 是 OH 和 U 是脂肪族桥基时，J 可以是烷氧基或苯氧基。这种化合物可用于纤维材料的染色或印花，染色或印花后的产品在各种牢度性能方面都具有优异的色彩和上色性能。
• Trisazo compound, method for dyeing by using it and ink containing it
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0645434A1

  公开（公告）日：1995-03-29

  A trisazo compound represented by the following formula (1) in the free acid form: wherein Q¹ is a phenylene group, Q² is a phenyl or naphtyl group, one of the A and B is a hydroxy group and the other is an amino group, K is 1 or 2, one of m and n is 1 and the other is 0, X and Y independently of one another are each -OR¹, -SR², -NR³R⁴ or wherein R¹, R², R³ and R⁴ independently of one another are each a hydrogen atom, an alkyl, phenyl or naphthyl group; r is 1 or 2; and Z is -CH₂-, -O-, -SO₂- or -NR⁵- wherein R⁵ is a hydrogen atom or C₁-C₄ alkyl group; a method for dyeing fiber material, paper or leather by using the trisazo compound; and an ink which contains the trisazo compound and which is excellent in storage stability and can give a clear black printed image having excellent water resistance and light fastness.

  游离酸形式的下式（1）所代表的三唑类化合物： 其中 Q¹ 为亚苯基，Q² 为苯基或萘基，A 和 B 中的一个为羟基，另一个为氨基，K 为 1 或 2，m 和 n 中的一个为 1，另一个为 0，X 和 Y 各自独立地为-OR¹、-SR²、-NR³R⁴ 或 其中 R¹、R²、R³ 和 R⁴ 各自独立地为氢原子、烷基、苯基或萘基；r 为 1 或 2；以及 Z 为 -CH₂-、-O-、-SO₂- 或 -NR⁵- 其中 R⁵ 为氢原子或 C₁-C₄ 烷基； 一种使用三唑化合物对纤维材料、纸张或皮革进行染色的方法； 以及一种含有三唑化合物的油墨，该油墨具有极佳的储存稳定性，可印制出清晰的黑色图像，并具有极佳的耐水性和耐光性。