(H2O)2(NO3)4(CH3OH)2Cd2(μ-N,N'-bis(3-pyridyl)isophthalamide)2 | 1160305-93-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (H2O)2(NO3)4(CH3OH)2Cd2(μ-N,N'-bis(3-pyridyl)isophthalamide)2
• CAS: 1160305-93-0
• 化学式: C₃₈H₄₀Cd₂N₁₂O₂₀
• 分子量: 1209.62
• InChiKey: VEDSRVNVIDAXON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 水 、 cadmium(II) nitrate tetrhydrate 、 1,3-bis(3-pyridyl)isophthalamide 以 甲醇 、 乙醇 为溶剂， 以40%的产率得到(H2O)2(NO3)4(CH3OH)2Cd2(μ-N,N'-bis(3-pyridyl)isophthalamide)2
  参考文献：
  名称：

  Ligating topology and counter anion controlled formation of discrete metallo-macrocycle and 2D corrugated sheet in coordination compounds derived from a bis-pyridyl-bis-amide ligand and Cd (II)salts

  摘要：

  Two coordination compounds namely [{(H2O)(2)(NO3)(4)(MeOH)(2)Cd-2(mu-L1)(2)}] 1 and [{(H2O)(2)Cd(mu-SO4)(mu-L1)}](n) 2 have been isolated by reacting a bis-pyridyl-bis-amide ligand namely N,N'-bis-(3-pyridyl)isophthalamide L1 with Cd(NO3)(2) and CdSO4, respectively. Single crystals of both 1 and 2 were determined. It was revealed from the X-ray analyses that conformation dependent ligating topology of L1 and different coordination modes of the counter anions (nitrate and sulfate) are responsible for the formation of discrete metallo-macrocycle (compound 1) and 2D corrugated sheet (compound 2). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.02.024