N-cyclohexylpropan-1-imine | 1195-49-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-cyclohexylpropan-1-imine
• 英文别名: N-(propylidene)-cyclohexylamine；N-propylidenecyclohexanamine；Propionaldehydcyclohexylimin
• CAS: 1195-49-9；27845-63-2
• 化学式: C₉H₁₇N
• 分子量: 139.241
• InChiKey: GVXRFUBCUFQTFF-NTMALXAHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  金刚烷酮 、 N-cyclohexylpropan-1-imine 在 草酸 、 lithium diisopropyl amide 作用下， 生成 2-tricyclo<3.3.1.13,7>decylidenepropanal
  参考文献：
  名称：

  通过单线态氧与手性烯丙醇的羟基导向 [2+2] 环加成反应形成高度非对映选择性的二氧杂环丁烷

  摘要：

  金刚烷基取代的烯丙醇 1a 与 CDCl3 中的单线态氧发生非对映选择性反应，生成二氧杂环丁烷 threo-2a，同时生成二氧戊环 4，后者作为初始烯反应的后续产物形成。在极性更大的 CD3OD/CCl4 溶剂混合物中，非对映选择性下降到 89:11，但烯模式（二氧戊环 4）被完全抑制。相比之下，醋酸盐 1b 在 CDCl3 和 CD3OD 中的光氧化仅产生烯产物 3b。观察到的苏式选择性羟基方向性是根据单线态氧和羟基之间的激基复合物中的氢键来解释的，后者通过 1,3-烯丙基应变在基底中适当地构象排列。

  DOI：

  10.1021/ja9835077

文献信息

• Microwave-Assisted Reactions of Schiff Bases with Diethyl Phosphonate in the Presence of CdI2
  作者：M. M. Kabachnik、E. V. Zobnina、I. P. Beletskaya

  DOI：10.1007/s11178-005-0194-y

  日期：2005.4

  The reaction of diethyl phosphonate with Schiff bases derived from aldehydes and ketones in the presence of cadmium iodide is strongly accelerated by microwave irradiation, and the corresponding α-aminophosphonates are formed in high yields.

  在碘化镉存在下，二乙基膦酸酯与由醛和酮衍生的席夫碱的反应在微波辐照下强烈加速，并且相应的高产率的α-氨基膦酸酯得以形成。
• Organic electroluminescence device
  申请人：Uetani Yasunori

  公开号：US20090015139A1

  公开（公告）日：2009-01-15

  An organic electroluminescence device wherein a light emitting layer exists between electrodes composed of an anode and a cathode, a layer (L) containing a polymer compound exists between the light emitting layer and the anode and the polymer compound contains a repeating unit of the following formula (1): (wherein, Ar 1 , Ar 2 , Ar 3 and Ar 4 represent each independently an arylene group or divalent heterocyclic group. E 1 , E 2 and E 3 represent each independently the following aryl group (A) or heterocyclic group (B). a and b represent each independently 0 or 1, and 0≦a+b≦1. Aryl group (A): aryl group having three or more substituents selected from alkyl groups, alkoxy groups and the like, Heterocyclic group (B): monovalent heterocyclic group having one or more substituents selected from alkyl groups, alkoxy groups and the like and in which the sum of the number of the substituents and the number of hetero atoms of the heterocycle is 3 or more.).

  一种有机电致发光器件，其包含一个发光层，该发光层位于由阳极和阴极组成的电极之间。在发光层和阳极之间存在一个含有聚合物化合物的层（L），该聚合物化合物包含以下式（1）的重复单元：（其中，Ar1，Ar2，Ar3和Ar4分别独立地表示芳基基团或二价杂环基团。E1，E2和E3分别独立地表示以下芳基基团（A）或杂环基团（B）。a和b分别独立地表示0或1，且0≦a+b≦1。芳基基团（A）：具有三个或更多取代基（例如烷基、烷氧基等）的芳基基团，杂环基团（B）：具有一个或多个取代基（例如烷基、烷氧基等）的一价杂环基团，且杂环的取代基数和杂原子数之和为3或更多）。
• COPOLYMER AND POLYMER LIGHT EMITTING DEVICE USING THE SAME
  申请人：Suzuki Tomoyuki

  公开号：US20100176376A1

  公开（公告）日：2010-07-15

  A copolymer comprising a repeating unit of the following formula (1) and a repeating unit of the following formula (2): (wherein, a ring A and ring B represent each independently an aromatic ring optionally having a substituent. X is —O—, —S—, —S(═O)—, —S(═O) 2 —, —Si(R 1 ) 2 —Si(R 1 ) 2 —, —Si(R 1 ) 2 —, —, —B(R 1 )—, —P(R 1 )—, —P(═O)(R 1 )—, —O—C(R 1 ) 2 — or —N═C(R 1 )—, and R 1 represents a substituent. When there are two or more R 1 s in the same formula, they may be the same or different.) (wherein, Y is —O—, —S— or —C(═O)—. Ar 1 represents an aryl group optionally having a substituent or a monovalent heterocyclic group optionally having a substituent, and there is no substituent connected to atoms of the ring of Ar 1 , the atoms being adjacent an atom of Ar 1 connected to a nitrogen atom in the formula. R 3 represents a substituent, and n represents an integer of from 0 to 3. When there are two or more R 2 s in the formula, they may be the same or different.).

  一种共聚物，包含如下式(1)的重复单元和如下式(2)的重复单元：（其中，环A和环B各自独立地表示具有取代基的芳香环。X是-O-、-S-、-S（═O）-、-S（═O）2-、-Si（R1）2-Si（R1）2-、-Si（R1）2-、-、-B（R1）-、-P（R1）-、-P（═O）（R1）-、-O-C（R1）2-或-N═C（R1）-，R1表示一个取代基。当在同一式中有两个或更多的R1时，它们可以相同或不同。）（其中，Y是-O-、-S-或-C（═O）-。Ar1表示一个具有取代基的芳基团或一个具有取代基的单价杂环基团，并且没有取代基连接到Ar1的环上的原子，这些原子相邻于公式中连接到氮原子的Ar1的原子。R3表示一个取代基，n表示从0到3的整数。当在公式中有两个或更多的R2时，它们可以相同或不同。）
• PYRENE POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Fukushima Daisuke

  公开号：US20100109517A1

  公开（公告）日：2010-05-06

  A polymer compound comprising a constitutional unit of the formula (1), and a repeating unit of any of the formulae (2) to (4): (wherein, x3, y1, y2, z1 to z3 are 0 or 1. y3 represents an integer of 0 to 2. u represents an integer of 0 to 8. Z represents a pyrene residue, Ar 1 represents an arylene group or di-valent heterocyclic group, and Ar 2 represents an aryl group or mono-valent heterocyclic group.)
• POLYMERIC MATERIAL AND POLYMERIC LUMINESCENT ELEMENT
  申请人：Nakatani Tomoya

  公开号：US20100171100A1

  公开（公告）日：2010-07-08

  A luminescent or charge-transporting polymer which has in the backbone optionally substituted fluorenediyl groups as repeating units and further has a functional side chain comprising at least one functional group selected from the group consisting of a hole-injection/transporting group containing one or more heteroatoms other than nitrogen or two or more nitrogen atoms, an electron-injection/transporting group containing one or more heteroatoms other than nitrogen or two or more nitrogen atoms, and a luminescent group comprising a fused aromatic hydrocarbon or heterocycle, characterized in that the functional group is directly bonded to the saturated carbon atom of any of the fluorenediyl groups or is bonded to any of the fluorenediyl groups through —R k —X— (R k represents alkylene and X represents a direct bond or connecting group) at the X.