Pyridinium, 4-ethenyl-1-methyl-, chloride | 45708-78-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Pyridinium, 4-ethenyl-1-methyl-, chloride
• 英文别名: 4-ethenyl-1-methylpyridin-1-ium;chloride
• CAS: 45708-78-9
• 化学式: C8H10ClN
• 分子量: 155.62
• InChiKey: TVIKPKVFMVKUGQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.84
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• HYDROCARBOXYLATION PROCESS
  申请人：Zoeller Joseph Robert

  公开号：US20070299280A1

  公开（公告）日：2007-12-27

  Disclosed is a hydrocarboxylation process for the production of carboxylic acid from olefins wherein an olefin, water, a Group VIII metal hydrocarboxylation catalyst, an onium salt compound are combined in a reaction zone and contacted with carbon monoxide under hydrocarboxylation conditions of pressure and temperature The process does not require or utilize the addition of a hydrogen halide or an alkyl halide exogenous or extraneous to the hydrocarboxylation process.

  揭示了一种从烯烃生产羧酸的羟基羧化过程，其中在反应区域中将烯烃、水、第VIII族金属羟基羧化催化剂和一个胞离子盐化合物结合，并在压力和温度的羟基羧化条件下与一氧化碳接触。该过程不需要或利用氢卤化物或烷基卤化物作为羟基羧化过程的外部添加物。
• CARBONYLATION PROCESS
  申请人：Zoeller Joseph Robert

  公开号：US20070293695A1

  公开（公告）日：2007-12-20

  Disclosed is a carbonylation process for the production of carboxylic acids, carboxylic acid esters and/or carboxylic acid anhydrides wherein a carbonylation feedstock compound selected from one or more organic oxygenates such as alcohols, ethers, and esters is contacted with carbon monoxide in the presence of a carbonylation catalyst and one or more onium compounds. The carbonylation process differs from known carbonylation processes in that a halide compound such as a hydrogen halide, typically hydrogen iodide, and/or alkyl halide, typically methyl iodide, extraneous or exogenous to the carbonylation process is not fed or supplied separately to the process.

  本发明揭示了一种用于生产羧酸、羧酸酯和/或羧酸酐的羰基化过程，其中选择一种或多种有机氧化物，例如醇、醚和酯的羰基化进料化合物，在羰基化催化剂和一种或多种离子化合物的存在下与一氧化碳接触。该羰基化过程不同于已知的羰基化过程，因为卤化物化合物，例如氢卤化物（通常为氢碘酸）和/或烷基卤化物（通常为碘甲烷），不是外部或外源性地提供给该过程。
• METHYL-IODIDE-FREE CARBONYLATION OF AN ALCOHOL TO ITS HOMOLOGOUS ALDEHYDE AND/OR ALCOHOL
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：US20160185700A1

  公开（公告）日：2016-06-30

  Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a single component catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 without additional promoters. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.

  本发明揭示了一种还原羰基化低分子量醇以产生同系醛和/或醇的方法。该方法包括在无需额外促进剂的情况下，使用钴、离子卡宾和碘的单组分催化剂复合物，在产生醛的反应中进行反应。在产生同系醇的过程中，使用钌协同催化剂。还原羰基化反应不需要额外的碘促进剂，并且产生的粗还原羰基化产物基本上不含有甲基碘。
• Process for coagulating fluoroelastomers
  申请人：Lyons Donald F.

  公开号：US20080194769A1

  公开（公告）日：2008-08-14

  In a process for the manufacture of fluoroelastomers, a coagulant is employed that is a water-soluble polymer having at least 2 quaternary onium centers. Specific examples of such coagulants include, but are not limited to poly(diallyldimethylammonium chloride), poly(epichlorohydrin-co-dimethyl amine), and poly(acrylamide-co-diallyldimethylammonium chloride).

  在制造氟弹性体的过程中，使用一种凝固剂，该凝固剂是一种水溶性聚合物，具有至少2个季铵中心。这种凝固剂的具体例子包括但不限于聚二甲基丙烯酰胺-二烯丙基二甲基铵盐、聚环氧氯丙烷-二甲基胺和聚丙烯酰胺-二烯丙基二甲基铵盐。
• Gel Formulations that are Stable for Storage, Comprising at Least Two Substantially Unmixed Hydrogels
  申请人：Sowa Christian

  公开号：US20110257016A1

  公开（公告）日：2011-10-20

  The present patent application relates to a gel formulation that is stable for storage, comprising at least two substantially un-mixed hydrogels, wherein each hydrogel contains at least one electrolyte-sensitive thickener. Also, one of the hydrogels (phase A) contains at least one material A that is not compatible with at least one of the materials B contained in another hydrogel (phase B), or that is not compatible therewith in the amounts in which said materials B are contained in the gel formulation.

  本专利申请涉及一种稳定的凝胶配方，包括至少两种基本未混合的水凝胶，其中每种水凝胶均包含至少一种电解质敏感的增稠剂。此外，其中一种水凝胶（A相）含有至少一种物质A，该物质A与另一种水凝胶（B相）中所含的至少一种物质B不兼容，或者不与该物质B在凝胶配方中所含的量兼容。