Mo3Te4(S2P(OPr(i))2)2(μ-benzoate)(tributylphosphine) | 285547-16-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Mo3Te4(S2P(OPr(i))2)2(μ-benzoate)(tributylphosphine)
• CAS: 285547-16-2
• 化学式: C₃₇H₇₄Mo₃O₈P₄S₆Te₄
• 分子量: 1761.5
• InChiKey: WNWBNKCENRGECQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Mo3Te4(S2P(OPr(i))2)2(μ-benzoate)(tributylphosphine) 以 not given 为溶剂， 生成 Mo3(μ3-Te)(μ-Te2)3(S2P(OPr(i))2)3I
  参考文献：
  名称：

  Syntheses and structures of two complexes with incomplete cuboidal Mo3Te44+ and Mo3(μ3-S)Te34+cluster cores

  摘要：

  The reaction of tributylphosphine, benzoic acid and Mo3Te7(S2P(OPri)(2))(3)I produced a new compound with triangular cluster skeleton Mo3Te44+, Mo3Te4[S2P(OPri)(2)](3)(mu-PhCO2)PBu3 (1). An unexpected compound including an Mo3Te3S4+ skeleton, Mo-3(mu(3)-S)Te-3- [S2P(OPri)(2)](3)(mu-PhNH2CO2)PBu3 (2), was obtained using aminobenzoic acid instead of benzoic acid. X-ray crystallographic analysis revealed that these complexes belong to the Mo3E44+ (E = S, Se, Te) incomplete cuboidal cluster family and are dimeric through the Te ... Te interaction. H-1 and P-31 NMR and IR spectroscopic data were also used to characterize these compounds. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00334-x
• 作为产物：
  描述：

  三丁基膦 、 Mo3(μ3-Te)(μ-Te2)3(S2P(OPr(i))2)3I 、 苯甲酸 以 乙醇 、 二氯甲烷 为溶剂， 以41%的产率得到Mo3Te4(S2P(OPr(i))2)2(μ-benzoate)(tributylphosphine)
  参考文献：
  名称：

  Syntheses and structures of two complexes with incomplete cuboidal Mo3Te44+ and Mo3(μ3-S)Te34+cluster cores

  摘要：

  The reaction of tributylphosphine, benzoic acid and Mo3Te7(S2P(OPri)(2))(3)I produced a new compound with triangular cluster skeleton Mo3Te44+, Mo3Te4[S2P(OPri)(2)](3)(mu-PhCO2)PBu3 (1). An unexpected compound including an Mo3Te3S4+ skeleton, Mo-3(mu(3)-S)Te-3- [S2P(OPri)(2)](3)(mu-PhNH2CO2)PBu3 (2), was obtained using aminobenzoic acid instead of benzoic acid. X-ray crystallographic analysis revealed that these complexes belong to the Mo3E44+ (E = S, Se, Te) incomplete cuboidal cluster family and are dimeric through the Te ... Te interaction. H-1 and P-31 NMR and IR spectroscopic data were also used to characterize these compounds. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00334-x