N-(1,3,2-benzodioxaphosphol-2-yl)-N-phenyl-1,3,2-benzodioxaphosphol-2-amine | 78543-73-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(1,3,2-benzodioxaphosphol-2-yl)-N-phenyl-1,3,2-benzodioxaphosphol-2-amine
• CAS: 78543-73-4
• 化学式: C₁₈H₁₃NO₄P₂
• 分子量: 369.253
• InChiKey: CUDJOYUZGVNTMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.89
• 重原子数：
  25.0
• 可旋转键数：
  3.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.16
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 N-(1,3,2-benzodioxaphosphol-2-yl)-N-phenyl-1,3,2-benzodioxaphosphol-2-amine 以 甲苯 为溶剂， 以85%的产率得到[(η(5)-C5H5)Ru(η(1)-(C6H4O2)PN(Ph)P(C6H4O2))2(PPh3)]Cl * PhMe
  参考文献：
  名称：

  Transition metal chemistry of phosphorus based ligands. Ruthenium(II) chemistry of bis(phosphino)amines, X2PN(R)PX2 (R=H or Ph, X=Ph; R=Ph, X2=O2C6H4)

  摘要：

  Reactions of CpRuCl(PPh3)(2) with bis(phosphino)amines, X2PN(R)PX2 (1 R = H, X = Ph; 2 R = X = Ph; 3 R = Ph, X-2 = O2C6H4) give neutral or cationic mononuclear complexes depending on the reaction conditions. Reaction of 1 with CpRuCl(PPh3)(2) gives one neutral complex, [CpRu(Cl)(eta(2)-Ph2PN(H)PPh2)] (4) and two cationic complexes, [CpRu(eta(2)-Ph2PN(H)PPh2)(eta(1)-Ph2PN(H)PPh2)]Cl (5) and [CpRu(PPh3)(eta(2)-Ph2PN(H)PPh2)]Cl (6), whereas the reaction of 2 with CpRuCl(PPh3)(2) leads only to the isolation of cationic complex, [CpRu(PPh3)(eta(2)-Ph2PN(Ph)PPh2)]Cl (7). The catechol derivative 3, in a similar reaction, affords an interesting mononuclear complex [CpRu(PPh3){eta(1)-(C4H4O2)PN(Ph)P(O2H4C6)}(2)]Cl (8) containing two monodentate bis(phosphino)amine ligands. The structural elucidation of the complexes was carried out by elemental analyses, IR and NMR spectroscopic data. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00464-1
• 作为产物：
  描述：

  a-丙烯酸氯甲酯 、 苯胺 在 三乙胺 作用下， 以 乙醚 为溶剂， 反应 16.0h， 以80%的产率得到N-(1,3,2-benzodioxaphosphol-2-yl)-N-phenyl-1,3,2-benzodioxaphosphol-2-amine
  参考文献：
  名称：

  Balakrishna, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2001, vol. 40, # 9, p. 976 - 978

  摘要：

  DOI：

文献信息

• phosphororganische Antioxidantien. XII. Synthesen und NMR-Spektren phosphororganischer Antioxidantien und verwandter Verbindungen
  作者：T. K�nig、W. D. Habicher、U. H�hner、J. Pionteck、C. R�ger、K. Schwetlick

  DOI：10.1002/prac.19923340407

  日期：——

  The syntheses of various aliphatic, aromatic, sterically hindered, and cyclic organophosphorus compounds (phosphorous acid esters, ester chlorides and ester amides, hydrogen phosphites, phosphonates and phosphates) are reported, and general procedures for preparation are given.The compounds synthesized were investigated by means of P-31-, H-1- and C-13-n.m.r. spectroscopy, and the chemical shifts measured are listed.