| 329201-81-2

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 329201-81-2
• 化学式: C₁₈H₂₄CuN₂O₄
• 分子量: 395.946
• InChiKey: XFYNDIMFDBDVCH-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N-(2-hydroxybenzyl) ethanolamine hydrochloride monohydrate 、 copper(II) perchlorate 在 aq.NaOH 作用下， 以 甲醇 为溶剂， 以94.7%的产率得到
  参考文献：
  名称：

  Synthesis, crystal structure and EPR of a hydrogen bonded two-dimensional network of Cu(II) complex with N-(2-hydroxybenzyl)-2-amino-1-ethanol

  摘要：

  Hsalea (N-(2-hydroxybenzyl)-2-amino-1-ethanol) and its Cu(II) complexes, Cu(salea)(2) (1) and CuH-1(salea).1.5H(2)O (2), were prepared and characterized. X-ray structural analyses of 1 show that two amino N and two deprotonated phenoxy O atoms of the two ligands coordinate equatorially to Cu(II). Two alcoholic O atoms coordinate weakly at axial positions. Each molecule utilizes two alcoholic H atoms and two phenoxy O atoms to form hydrogen bonds with four surrounding molecules, leading to a two-dimensional network structure. EPR and electronic spectra of 1 are consistent with the elongated octahedral coordination polyhedron. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00261-9