dichloropentaphenoxy(2-pyridylmethylamino)cyclotriphosphazeneplatinum(II) | 185419-94-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dichloropentaphenoxy(2-pyridylmethylamino)cyclotriphosphazeneplatinum(II)
• 英文别名: dichloroplatinum;2,4,4,6,6-pentaphenoxy-N-(pyridin-2-ylmethyl)-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-trien-2-amine
• CAS: 185419-94-7
• 化学式: C₃₆H₃₂Cl₂N₅O₅P₃Pt
• 分子量: 973.588
• InChiKey: AKJUYUHXVTVMJU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [PtCl₄(EtCN)2] 、 pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene 以 氯仿 为溶剂， 以6%的产率得到dichloropentaphenoxy(2-pyridylmethylamino)cyclotriphosphazeneplatinum(II)
  参考文献：
  名称：

  Reactions of platinum nitrile complexes with cyclotriphosphazenes containing pyridylalkylamino groups

  摘要：

  Reactions of platinum(II) and platinum(IV) nitrile complexes with polydentate ligands, such as pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene, pentaphenoxy(3-pyridylmethylamino)cyclotriphosphazene, and pentaphenoxy(2-pyridylethylamino)cyclotriphosphazene, were studied. Platinum(IV) is reduced to platinum(II) upon complex formation; the pyridine and alkylamine nitrogen atoms coordinate to platinum(II) to form chelate rings. The compounds obtained were characterized by H-1 and P-31 NMR and IR spectroscopy, FAB mass spectrometry, and other methods.

  DOI：

  10.1134/s1070363206040074

文献信息

• Phosphazenes with (2‐Pyridylmethylamino) Groups, I. Syntheses and Crystal Structures of Pentaphenoxy(2‐pyridylmethylamino)‐cyclotriphosphazene and Its Copper(II) Nitrate, Platinum (II) Chloride, and Cobalt(II) Nitrate Complexes
  作者：Ursula Diefenbach、Michael Kretschmann、Brigitte Stromburg

  DOI：10.1002/cber.19961291227

  日期：1996.12

  The reaction of the (2-pyridylmethylamino)-substituted cyclotriphosphazene N3P3(OC6H5)5(NHCH2(C5H4N)-2) (1) with copper(II) nitrate, platinum(II) chloride, and cobalt(II) nitrate yields the stable complexes [Cu(NO3)2·(1)2] (1a), [PtCl2·(1)] (1b), [Co(NO3)2 · (1)] (1c). The X-ray crystallographic studies of these metal complexes revealed the different coordination behavior of the multifunctional ligand

  （2-吡啶基甲基氨基）取代的环三磷腈N 3 P 3（OC 6 H 5）5（NHCH 2（C 5 H 4 N）-2）（1）与硝酸铜（II），铂（II）的反应氯化物和硝酸钴（II）生成稳定的络合物[Cu（NO 3）2 ·（1）2 ]（1a），[PtCl 2 ·（1）]（1b），[Co（NO 3）2 ·（1）]（1c）。这些金属配合物的X射线晶体学研究揭示了多功能配体的不同配位行为。
• Synthesis and molecular structure of platinum(II) complexes with cyclotriphosphazenes containing pyridylalkylamino and pyridylmethoxy groups
  作者：S. A. Simanova、T. V. Kuznetsova、V. N. Demidov、E. A. Aleksandrova、U. Diefenbach

  DOI：10.1134/s1070363207110059

  日期：2007.11

  The interaction of platinum(II) nitrile complexes with polydentate ligands, pentaphenoxy(2-pyridylmethylamino) cyclotriphosphazene (L-1), pentaphenoxy( 3-pyridylmethylamino) cyclotriphosphazene (L-2), pentaphenoxy[2-(2- pyridyl) ethylamino] cyclotriphosphazene (L-3), and pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene (L-4), was studied. The synthesized complexes were characterized by single-crystal X-ray diffraction, H-1 and P-31 NMR spectroscopy, IR spectroscopy, FAB mass spectrometry, and other methods. In complexation of phosphazenes L-1 L-3 with Pt(II) ions, nitrogen atoms of the pyridine ring and alkylamine fragment participate in the coordination to form chelate rings. In the complex with L-4, the substituted phosphazene is coordinated via nitrogen atoms of the pyridyl group and cyclotriphosphazene ring to form a seven-membered ring.