[ZnBr2(α-picoline N-oxide)2] | 18024-31-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [ZnBr2(α-picoline N-oxide)2]
• 英文别名: [ZnBr2(α-picoNO)2]；dibromozinc;2-methyl-1-oxidopyridin-1-ium
• CAS: 18024-31-2
• 化学式: C₁₂H₁₄Br₂N₂O₂Zn
• 分子量: 443.453
• InChiKey: QMILPHCOBLJPLV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基吡啶氧化物 、 zinc dibromide 以 not given 为溶剂， 生成 [ZnBr2(α-picoline N-oxide)2]
  参考文献：
  名称：

  某些二价过渡金属溴化物的-甲基吡啶-N-氧化物加合物的热化学参数

  摘要：

  碱性层状钛酸酯（K 2 Ti 4 O 9 和Na 2 Ti 3 O 7 ）与酸溶液反应，生成存在于其中的K + 和Na + 离子的部分离子交换。 H + 质子形成层间区域，生成钛酸形式。这些材料通过X射线衍射，红外光谱和热分析（TG / DTA）进行了表征。

  DOI：

  10.1007/s10973-005-0064-4

文献信息

• A study on the reactivity of cobalt, copper and zinc complexes of 2-methylpyridine-N-oxide towards sulfur dioxide
  作者：M. Fondo、M.R. Bermejo、A. Sousa、J. Sanmartín、M.I. Fernández、C.A. McAuliffe

  DOI：10.1016/s0277-5387(97)00387-2

  日期：1998.1

  A series of complexes of general formula M(2-PyCO)(n)X-2(H2O)(m) (M = Co, Cu, Zn; 2-PyCO = 2-methylpyridine-N-oxide, n = 1-2, X = Cl, Br, I and NO3 and m = 0-1) has been prepared and characterised. The reactivity of these complexes with sulfur dioxide has been investigated in the solid state and in toluene slurries at room temperature. The effect of temperature on the ability of these-complexes to hx SO2 has been studied by thermogravimetrical analysis (TGA); the temperature range of study depending critically on the melting point of the initial precursors. The same technique has been used to study the reversibility of the reaction with sulfur dioxide.The amount of sulfur dioxide fixed is dependent on the metal, the anion, the medium of the reaction and the temperature. In general, an increase in temperature results in a decrease in the reactivity of the metal precursors with SO2 but the complexes of copper halides show that an increase in temperature favours the reaction. This is quite interesting behaviour not previously reported. (C) 1998 Elsevier Science Ltd. All rights reserved.