Infrared spectra (1650–400 cm.<sup>–1</sup>) of γ-picoline metal co-ordination complexes
作者:M. Goodgame、P. J. Hayward
DOI:10.1039/j19660000632
日期:——
Infraredspectra (1650–400 cm.–1) are reported for the following complexes of γ-picoline (L): ML4X2(M = Mn or Ni, X = Cl, Br, or I; M = Fe, X = Br; M = Co, X = Cl, Br, I, or NCS), ML2X2(M = Mn, Cu, Zn, X = Cl; M = Co, X = Cl, Br, or I; M = Ni, X = Br or I), and MLX2(M = Mn, Ni, X = Cl). The changes from the spectrum of the free ligand are related to the polarising power of the metal ion and the geometry
报道了以下γ-甲基吡啶(L)配合物的红外光谱(1650–400 cm。–1):ML 4 X 2(M = Mn或Ni,X = Cl,Br或I; M = Fe,X = Br; M = Co,X = Cl,Br,I或NCS),ML 2 X 2(M = Mn,Cu,Zn,X = Cl; M = Co,X = Cl,Br或I; M = Ni,X = Br或I)和MLX 2(M = Mn,Ni,X = Cl)。游离配体光谱的变化与金属离子的极化能力和配合物的几何形状有关。