4-benzamidopentan-2-yl benzoate | 102177-94-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-benzamidopentan-2-yl benzoate
• CAS: 102177-94-6
• 化学式: C₁₉H₂₁NO₃
• 分子量: 311.381
• InChiKey: COQGNYVGVVVZGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS
  申请人：TAFTAF Mansour

  公开号：US20160340293A1

  公开（公告）日：2016-11-24

  A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R 8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

  一种催化剂组合物，包括作为内部电子给体的化合物I的公式，其中：R1、R2、R3、R4、R5和R6分别独立地选择自由氢、直链、支链和环烷基和芳香族取代和未取代的烃基，碳原子数为1至20；R7选择自由直链、支链和环烷基和芳香族取代和未取代的烃基，碳原子数为1至20；R8选择自由芳香族取代和未取代的烃基，碳原子数为6至20。还公开了制备所述聚合催化剂组合物的方法；包括所述催化剂组合物、共催化剂和可选的外部电子给体的聚合催化剂体系；通过该方法可获得的聚烯烃；以及在烯烃聚合催化剂中使用化合物I作为内部电子给体的用途。
• Halogenated Amide Ester and Internal Electron Donor with Same
  申请人：Chen Linfeng

  公开号：US20120322964A1

  公开（公告）日：2012-12-20

  Disclosed are halogenated amide esters that are suitable as internal electron donors in procatalyst compositions. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.

  揭示了适用作为内部电子给体的卤代酰胺酯在前催化剂组合物中。含有这种前催化剂组合物的齐格勒-纳塔催化剂组合物表现出改善的催化剂活性和/或改善的催化剂选择性，并生产具有广泛分子量分布的丙烯基烯烃。
• Catalyst composition for polymerization of olefins
  申请人：SAUDI BASIC INDUSTRIES CORPORATION

  公开号：US10059656B2

  公开（公告）日：2018-08-28

  A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R1, R2, R3, R4, R5 and R6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

  一种催化剂组合物，包括作为内部电子供体的式 I 化合物、 其中 R1、R2、R3、R4、R5 和 R6 独立地选自氢、具有 1 至 20 个碳原子的直链、支链和环状烷基以及芳香取代和未取代的烃基；R7 选自具有 1 至 20 个碳原子的直链、支链和环状烷基以及芳香取代和未取代的烃基；以及 R8 选自具有 6 至 20 个碳原子的芳香取代和未取代的烃基。还公开了制备所述聚合催化剂组合物的工艺；包含所述催化剂组合物、助催化剂和可选的外部电子供体的聚合催化剂体系；可通过该工艺获得的聚烯烃；以及式 I 化合物作为内部电子供体在烯烃聚合催化剂中的用途。
• HALOGENATED AMIDE ESTER AND INTERNAL ELECTRON DONOR WITH SAME
  申请人：W.R. Grace & CO. - CONN.

  公开号：EP2539378B1

  公开（公告）日：2018-06-06
• AMIDE ESTER INTERNAL ELECTRON DONOR AND PROCESS
  申请人：W.R. GRACE & CO.-CONN.

  公开号：EP2539379B1

  公开（公告）日：2017-09-06