(E)-2-((isobutylimino)methyl)phenol | 135609-64-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (E)-2-((isobutylimino)methyl)phenol
• 英文别名: N-Salicyliden-isobutylamin；N-Isobutyl-salicylaldimin
• CAS: 135609-64-2
• 化学式: C₁₁H₁₅NO
• 分子量: 177.246
• InChiKey: CKIARBBSWICEEJ-XYOKQWHBSA-N

物化性质

• 沸点：
  279.6±23.0 °C(Predicted)
• 密度：
  0.97±0.1 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  异丁胺 、 水杨醛 以 甲苯 为溶剂， 反应 26.0h， 以97%的产率得到(E)-2-((isobutylimino)methyl)phenol
  参考文献：
  名称：

  海洋盐藻和迷迭香属细菌中的含氮挥发物

  摘要：

  细菌可产生多种挥发性化合物。这些挥发性物质中很多都携带氧气，而含氮挥发性物质则较少见。我们在此报告了从盐藻CNS863鉴定和合成新的含氮挥发物的报告，并探讨了另一种细菌谱系中的发生，例如玫瑰杆菌属细菌。鉴定了以前从未从细菌中报告过的几种化合物类别，例如二烷基脲和草酰胺。以前从未报道过将亚磺酰胺作为天然产物。放线菌S.茵CNS863产生，例如，亚磺酰胺Ñ -异丁基-和Ñ -isopentylmethanesulfinamide（5，6），尿素Ñ，Ñ ' - diisobutylurea（16），和草酰胺Ñ，Ñ ' - diisobutyloxalamide（17）。另外，新的亚胺如（E）-1-（呋喃-2-基）-N-（2-甲基丁基）甲亚胺（8）和（E）-2-（（异丁基亚氨基）甲基）苯酚（13）。与其他几种亚胺，乙酰胺和甲酰胺一起鉴定。这些化合物中的一些（包括亚磺酰胺）也被玫瑰细菌群细菌Roseovarius

  DOI：

  10.1021/acs.jnatprod.7b00789

文献信息

• METHOD FOR THE PREPARATION OF COPOLYMERS OF ETHYLENE/NORBORNENE-TYPE MONOMERS WITH NICKEL CATALYSTS
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0988330A1

  公开（公告）日：2000-03-29
• Use of a Combination Chain Transfer and Activating Agent to Control Molecular Weight and Optical Density of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20080242810A1

  公开（公告）日：2008-10-02

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
• Use Of A Combination Chain Transfer And Activating Agent To Control Molecular Weight And Optical Density Of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20110009578A1

  公开（公告）日：2011-01-13

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
• US5929181A
  申请人：——

  公开号：US5929181A

  公开（公告）日：1999-07-27
• US6197984B1
  申请人：——

  公开号：US6197984B1

  公开（公告）日：2001-03-06