| 883884-45-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 883884-45-5
• 化学式: C₂₁H₂₄CoN₂O₂
• 分子量: 395.427
• InChiKey: ICSVVUKVASJIDQ-YXEBPMGASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(nitriloethylidyne)]bis[phenol] 、 cobalt(II) diacetate tetrahydrate 以 丙醇 为溶剂， 生成
  参考文献：
  名称：

  Oxidation of cyclohexene with tert-butylhydroperoxide and hydrogen peroxide catalysted by Cu(II), Ni(II), Co(II) and Mn(II) complexes of N,N′-bis-(α-methylsalicylidene)-2,2-dimethylpropane-1,3-diamine, supported on alumina

  摘要：

  New square-planar manganese(II), copper(II), nickel(II) and cobalt(II) complexes of a tetradentate Schiff-base ligand "N,N'-bis-(alpha-methylsalicylidene)-2,2-dimethylpropane-1,3-diamine", H-2[Me(2)salpnMe(2)] have been prepared and characterized by elemental analyses, IR, UV-vis, conductometric and magnetic measurements. The results suggest that the symmetrical Schiff-base is a bivalent anion with tetradentate ONNO donors derived from the phenolic oxygen and azomethine nitrogen. The formulae was found to be [M(Me(2)salpnMe(2))] for the 1:1 non-electrolytic complexes. Alumina-supported metal complexes (ASMC); [M(Me(2)salpnMe(2))]/Al2O3; catalyze the oxidation of cyclohexene with tert-buthylhydroperoxide (TBHP) and hydrogen peroxide. Oxidation of cyclohexene with TBHP gave 2-cyclohexene-1-one, 2-cyclohexene-2-ol and 1-(tert-butylperoxy)-2-cyclohexene whereas, oxidation with H2O2 resulted in the formation of cyclohexene oxide and cyclohexene-1,2-diol. Manganese(II) complex supported on alumina "[Mn(Me(2)salpnMe(2))]/Al2O3" shows significantly higher catalytic activity than other catalysts. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.05.026