Zn2Mn(OAc)6(bpy)2 | 1259288-14-6

• 英文名称: Zn2Mn(OAc)6(bpy)2
• 英文别名: Zn2Mn(acetate)6(2,2'-bipyridine)2
• CAS: 1259288-14-6
• 化学式: C₃₂H₃₄MnN₄O₁₂Zn₂
• 分子量: 852.36
• InChiKey: VRRAHDLERHYKJE-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Zn2Mn(OAc)6(bpy)2 以 neat (no solvent, solid phase) 为溶剂， 生成 zinc manganese oxide 、 zincite
  参考文献：
  名称：

  Heterometallic M/Mn (M=Cu, Co, Zn) acetate complexes as precursors for binary oxides

  摘要：

  A facile one-pot procedure, or so-called "direct synthesis," was used to prepare the novel heterometallic complexes [M(2)Mn(OAc)(6)(bpy)(2)], where M=Cu (1), Co (2), Zn (3), bpy=2,2'-bipyridyl, with high yields via oxidative dissolution of pure metals in a liquid phase. The complexes were characterized by an elemental analysis, single crystal X-ray diffraction method and FTIR. These complexes are proposed as precursors, whose thermal degradation may lead to the formation of solids possessing nano- to microsize levels of dispersity. The thermal behavior of the complexes obtained was studied by thermal analysis (TG/DTA/DTG) in both air and N(2) and also by TPD mass-spectrometry in vacua. The FTIR, X-ray powder diffraction (PXRD) and thermoanalytical data were used for the identification of the solid products of thermal degradation. The morphology and microstructure of the solid residues were analyzed, using scanning electron microscopy with energy dispersive X-ray microanalysis (SEM/EDX) at mkm and sub-micro levels. (C) 2010 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2010.08.040
• 作为产物：
  描述：

  乙酸铵 、 2,2'-联吡啶 、 manganese (II) acetate tetrahydrate 、 锌 以 甲醇 为溶剂， 以78%的产率得到Zn2Mn(OAc)6(bpy)2
  参考文献：
  名称：

  Heterometallic M/Mn (M=Cu, Co, Zn) acetate complexes as precursors for binary oxides

  摘要：

  A facile one-pot procedure, or so-called "direct synthesis," was used to prepare the novel heterometallic complexes [M(2)Mn(OAc)(6)(bpy)(2)], where M=Cu (1), Co (2), Zn (3), bpy=2,2'-bipyridyl, with high yields via oxidative dissolution of pure metals in a liquid phase. The complexes were characterized by an elemental analysis, single crystal X-ray diffraction method and FTIR. These complexes are proposed as precursors, whose thermal degradation may lead to the formation of solids possessing nano- to microsize levels of dispersity. The thermal behavior of the complexes obtained was studied by thermal analysis (TG/DTA/DTG) in both air and N(2) and also by TPD mass-spectrometry in vacua. The FTIR, X-ray powder diffraction (PXRD) and thermoanalytical data were used for the identification of the solid products of thermal degradation. The morphology and microstructure of the solid residues were analyzed, using scanning electron microscopy with energy dispersive X-ray microanalysis (SEM/EDX) at mkm and sub-micro levels. (C) 2010 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2010.08.040