(dmit)(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II) | 622828-87-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (dmit)(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II)
• CAS: 622828-87-9
• 化学式: C₁₉H₁₀N₂PdS₉
• 分子量: 661.316
• InChiKey: RZRVWHJHCJZTNL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (dmit)(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II) 、 碘 以 氯仿 为溶剂， 生成 [(dmit)(4',5'-diaza-9'-(4,5-bis(methylthio)-1,3-dithiole-2-ylidene)-fluorene)palladium(II)]I0.41
  参考文献：
  名称：

  ‘Unsymmetric’ palladium(II) complexes with ligand 4′,5′-diaza-9′-(4,5-disubstituted-1,3-dithiole-2-ylidene)-fluorene

  摘要：

  Four 'unsyminetric' complexes of palladium(II), [Pd(L)Cl-2] and [Pd(L)(dmit)], have been synthesized and characterized [L = 4', 5'-diaza-9'-(4.5-bis(methylthio)-1,3-dithiole-2-ylidene)-fluorene (L-1) and 4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene (L-2)]. Single crystal Structure of [Pd(L-1)Cl-2] was determined, in which, the atoms of the molecule, except two methyl-groups, are conjugated in a quasi-plane. The planar molecules are further stacked forming two unequivalent columns with C...C, S...C and S...Cl contacts. The differences between dichloro complexes and dmit complexes in IR, UV and oxidation properties were discussed in detail. The dmit complexes exhibit LLCT hand from dmit (donor) to pi* of L-1 (acceptor). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00176-2
• 作为产物：
  描述：

  4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene 在 methanate sodium 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 (dmit)(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II)
  参考文献：
  名称：

  ‘Unsymmetric’ palladium(II) complexes with ligand 4′,5′-diaza-9′-(4,5-disubstituted-1,3-dithiole-2-ylidene)-fluorene

  摘要：

  Four 'unsyminetric' complexes of palladium(II), [Pd(L)Cl-2] and [Pd(L)(dmit)], have been synthesized and characterized [L = 4', 5'-diaza-9'-(4.5-bis(methylthio)-1,3-dithiole-2-ylidene)-fluorene (L-1) and 4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene (L-2)]. Single crystal Structure of [Pd(L-1)Cl-2] was determined, in which, the atoms of the molecule, except two methyl-groups, are conjugated in a quasi-plane. The planar molecules are further stacked forming two unequivalent columns with C...C, S...C and S...Cl contacts. The differences between dichloro complexes and dmit complexes in IR, UV and oxidation properties were discussed in detail. The dmit complexes exhibit LLCT hand from dmit (donor) to pi* of L-1 (acceptor). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00176-2