外消旋-反式-1,2-双[二(3,5-二甲基苯基)膦基甲基]环丁烷 | 1226906-44-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 外消旋-反式-1,2-双[二(3,5-二甲基苯基)膦基甲基]环丁烷
• 英文名称: racemic-trans-1,2-Bis[di(3,5-dimethylphenyl)phosphinomethyl]cyclobutane
• 英文别名: [2-[bis(3,5-dimethylphenyl)phosphanylmethyl]cyclobutyl]methyl-bis(3,5-dimethylphenyl)phosphane
• CAS: 1226906-44-0
• 化学式: C₃₈H₄₆P₂
• 分子量: 564.7
• InChiKey: REZOVLQIMMUCQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  40
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• PRODUCING BDO VIA HYDROFORMYLATION OF ALLYL ALCOHOL MADE FROM GLYCERIN
  申请人：Lyondell Chemical Technology, L.P.

  公开号：US20190263737A1

  公开（公告）日：2019-08-29

  A method including hydroformylating, with syngas, allyl alcohol in an allyl alcohol feed, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; and producing a 1,4-butanediol (BDO) product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product. A method including hydroformylating, with syngas, allyl alcohol in a feed comprising bio-allyl alcohol, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; and producing a BDO product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product. A method including hydroformylating, with syngas, bio-allyl alcohol in a feed comprising bio-allyl alcohol, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; producing a BDO product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product; and removing a byproduct of the production of the bio-allyl alcohol prior to hydroformylating the bio-allyl alcohol and/or from the BDO-product.

  一种方法包括使用合成气对丙烯醇进行氢甲酰化，以产生含有4-羟基丁醛和3-羟基-2-甲基丙醛的氢甲酰化产物；并通过对至少部分氢甲酰化产物进行加氢，生产包括丁二醇和1,3-甲基丙二醇的1,4-丁二醇（BDO）产品。一种方法包括使用合成气对含有生物丙烯醇的进料中的丙烯醇进行氢甲酰化，以产生含有4-羟基丁醛和3-羟基-2-甲基丙醛的氢甲酰化产物；并通过对至少部分氢甲酰化产物进行加氢，生产包括丁二醇和1,3-甲基丙二醇的BDO产品。一种方法包括使用合成气对含有生物丙烯醇的进料中的生物丙烯醇进行氢甲酰化，以产生含有4-羟基丁醛和3-羟基-2-甲基丙醛的氢甲酰化产物；通过对至少部分氢甲酰化产物进行加氢，生产包括丁二醇和1,3-甲基丙二醇的BDO产品；并在氢甲酰化生产生物丙烯醇之前或从BDO产品中去除生物丙烯醇生产的副产物。
• High linear selectivity ligand for allyl alcohol hydroformylation
  申请人：Lyondell Chemical Technology, L.P.

  公开号：US10807934B1

  公开（公告）日：2020-10-20

  A process for selectively producing 4-hydroxybutyraldehyde from allyl alcohol is described. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solvent and a catalyst system comprising a rhodium complex and a trans-1,2-bis(bis(3,4,5-tri-n-alkylphenyl)phosphinomethyl)-cyclobutane. The process gives high yield of 4-hydroxybutyraldehyde compared to temperature.

  本发明描述了一种从丙烯醇选择性地生产4-羟基丁醛的过程。该过程包括在溶剂和催化剂体系的存在下，将丙烯醇与一种混合物（包括一氧化碳和氢气）反应，所述催化剂体系包括一个铑配合物和一个trans-1,2-双（双（3,4,5-三-n-烷基苯基）磷酰甲基）环丁烷。与温度相比，该过程可以高产得4-羟基丁醛。
• IMPROVING RHENIUM CATALYSTS FOR GLYCERIN TO ALLYL ALCOHOL CONVERSION
  申请人：Lyondell Chemical Technology, L.P.

  公开号：EP3530644A1

  公开（公告）日：2019-08-28

  A catalyst system for the conversion of glycerin to allyl alcohol, the catalyst system comprising: a rhenium compound selected from rhenium dioxide, rhenium trioxide, and a combination thereof. A method of producing allyl alcohol from glycerin via the catalyst system, the method comprising exposing glycerin to a temperature of greater than 140°C in the presence of a catalyst comprising rhenium trioxide, rhenium dioxide, or a combination thereof to produce a product comprising allyl alcohol.

  一种将甘油转化为烯丙基醇的催化剂系统，该催化剂系统包括：选自二氧化铼、三氧化铼及其组合的铼化合物。一种通过催化剂系统从甘油中生产烯丙醇的方法，该方法包括在由三氧化铼、二氧化铼或它们的组合组成的催化剂存在下，将甘油暴露在高于140℃的温度下，以生产包含烯丙醇的产品。
• Producing BDO via hydroformylation of allyl alcohol made from glycerin
  申请人：Lyondell Chemical Technology, L.P.

  公开号：US10919023B2

  公开（公告）日：2021-02-16

  A method including hydroformylating, with syngas, allyl alcohol in an allyl alcohol feed, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; and producing a 1,4-butanediol (BDO) product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product. A method including hydroformylating, with syngas, allyl alcohol in a feed comprising bio-allyl alcohol, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; and producing a BDO product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product. A method including hydroformylating, with syngas, bio-allyl alcohol in a feed comprising bio-allyl alcohol, to produce a hydroformylation product comprising 4-hydroxybutyraldehyde and 3-hydroxy-2-methylpropionaldehyde; producing a BDO product comprising BDO and 1,3-methylpropanediol via hydrogenation of at least a portion of the hydroformylation product; and removing a byproduct of the production of the bio-allyl alcohol prior to hydroformylating the bio-allyl alcohol and/or from the BDO-product.

  一种方法，包括用合成气将烯丙基醇进料中的烯丙基醇进行加氢甲酰化，生成包括4-羟基丁醛和3-羟基-2-甲基丙醛的加氢甲酰化产物；以及通过对至少一部分加氢甲酰化产物进行氢化，生成包括BDO和1,3-甲基丙二醇的1,4-丁二醇（BDO）产物。一种方法，包括用合成气对包含生物烯丙基醇的进料中的烯丙基醇进行加氢甲酰化，生成包含 4-羟基丁醛和 3-羟基-2-甲基丙醛的加氢甲酰化产物；以及通过加氢甲酰化产物的至少一部分进行氢化，生成包含 BDO 和 1,3-甲基丙二醇的 BDO 产物。一种方法，包括在包含生物烯丙基醇的进料中用合成气对生物烯丙基醇进行加氢甲酰化，以生产包含 4-羟基丁醛和 3-羟基-2-甲基丙醛的加氢甲酰化产物；通过加氢甲酰化产物中至少一部分的氢化反应，生产由 BDO 和 1,3-甲基丙二醇组成的 BDO 产物；以及在对生物烯丙基醇进行加氢甲酰化之前和/或从 BDO 产物中去除生产生物烯丙基醇的副产物。
• Rhenium catalysts for glycerin to allyl alcohol conversion
  申请人：Lyondell Chemical Technology, L.P.

  公开号：US10919024B2

  公开（公告）日：2021-02-16

  A catalyst system for the conversion of glycerin to allyl alcohol, the catalyst system comprising: a rhenium compound selected from rhenium dioxide, rhenium trioxide, and a combination thereof. A method of producing allyl alcohol from glycerin via the catalyst system, the method comprising exposing glycerin to a temperature of greater than 140° C. in the presence of a catalyst comprising rhenium trioxide, rhenium dioxide, or a combination thereof to produce a product comprising allyl alcohol.

  一种将甘油转化为烯丙基醇的催化剂系统，该催化剂系统包括：选自二氧化铼、三氧化铼及其组合的铼化合物。一种通过催化剂系统从甘油生产烯丙醇的方法，该方法包括在由三氧化铼、二氧化铼或它们的组合组成的催化剂存在下，将甘油暴露在高于140℃的温度下，以生产包含烯丙醇的产品。