Cu(salycilideneanthranilate-H)(2-ethylimidazole) | 195974-60-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu(salycilideneanthranilate-H)(2-ethylimidazole)
• 英文别名: Cu(SAA)(EtImH)
• CAS: 195974-60-8
• 化学式: C₁₉H₁₇CuN₃O₃
• 分子量: 398.908
• InChiKey: QBGIOOAZMCCUMU-CBNWXSEKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-乙基咪唑 、 以 乙醇 、 水 为溶剂， 以70%的产率得到Cu(salycilideneanthranilate-H)(2-ethylimidazole)
  参考文献：
  名称：

  Synthesis and X-Band Epr Spectra of Binary and Ternary Complexes of Copper(II) with Salicylideneanthranilic Acid and Imidazoles

  摘要：

  The synthesis and EPR spectra of some binary and ternary complexes of copper(II) with a terdentate ligand, salicylideneanthranilic acid (H(2)SAA) and some monodentate imidazoles viz. imidazole (im) and 2-ethylimidazole (e-im), are described. The binary complex with copper(II) and salicylideneanthranilic acid shows a subnormal magnetic moment and EPR spectra for spin-spin interaction. The zero-field splitting parameter D has been evaluated as 190 G and the copper-copper distance as 5.227 Angstrom. The ternary complexes show magnetic moments and EPR spectra which suggest a distorted tetrahedral geometry around copper(II).

  DOI：

  10.1080/00945719708000253

文献信息

• Synthesis, structure and properties of some copper(II) complexes containing an ONO donor Schiff base and substituted imidazole ligands
  作者：R.N. Patel、V.L.N. Gundla、D.K. Patel

  DOI：10.1016/j.poly.2007.11.042

  日期：2008.2

  Five new mixed ligand coper(II) complexes, viz. [Cu(SAA)(H2O)] (1), [Cu(SAA)(MeImH)] (2), [Cu(SAA)(EtImH)] (3), [Cu(SAA)-(BenzImH)] (4) and [Cu(SAA)(MebenzImH)] (5), where SAA = salicylideneanthranilic acid, MeImH = 2-methylimidazole, EtImH = 2-ethylimidazole, BenzlmH - benzimidazole, MebenzImH = 2-methylbenzimidazole, have been synthesized and characterized by means of elemental analysis, FAB mass spectrometry, magnetic susceptibility, X-band EPR, electronic spectroscopy, IR and cyclic voltammetry. The frozen solution EPR spectra of the complexes have shown axial features. Single crystal X-ray analysis of 2 and 3 has revealed the presence of a distorted square planar geometry (N2O2) in the complexes. The superoxide dismutase (SOD) activity of the present complexes has also been measured and discussed. (C) 2008 Elsevier Ltd. All rights reserved.