1-(allyloxy)-2,3-dihydroxy benzene | 58169-20-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1-(allyloxy)-2,3-dihydroxy benzene
• 英文别名: 3-Allyloxycatechol；3-prop-2-enoxybenzene-1,2-diol
• CAS: 58169-20-3
• 化学式: C₉H₁₀O₃
• 分子量: 166.177
• InChiKey: LOGKQZXEKNSOQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(allyloxy)-2,3-dihydroxy benzene 、 1,2-二氯乙烷 以81%的产率得到
  参考文献：
  名称：

  FUJITA HARUSHIGE; YAMASHITA MASATARO, YUKI GOSEI KAGAKU KYOKAI SHI, J. SOC. ORG. SYN. CHEM., TOKYO , 1+

  摘要：

  DOI：
• 作为产物：
  描述：

  4-Allyloxy-2-ethoxy-1,3-benzodioxolane 、 对甲苯磺酸一水合物 、 碳酸氢钠 在 甲醇 、 甲基叔丁基醚 、 Sodium sulfate-III 作用下， 以 甲醇 为溶剂， 反应 16.0h， 以to give 39 compound (2.4 g, 95%) which的产率得到1-(allyloxy)-2,3-dihydroxy benzene
  参考文献：
  名称：

  Compositions and methods with enhanced therapeutic activity

  摘要：

  小说醌和邻苯二酚组成物，含有醌和邻苯二酚组成物的前药的组成物，以及用于治疗实体肿瘤癌和其他血管增生性疾病的使用方法。本公开特别涉及发现具有双重活性的药剂，能够产生血管靶向效应和直接肿瘤细胞细胞毒作用，以实现患者的增强抗肿瘤反应。

  公开号：

  US08198302B2

文献信息

• Monofunctionalization of phenolic hydroxy onto a polyphenol
  申请人：Roussel Uclaf

  公开号：US05198571A1

  公开（公告）日：1993-03-30

  A region-specific monofunctionalization of a phenolic hydroxy onto a polyphenol for the preparation of a compound of the formula ##STR1## wherein R is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, --CN, formyl, carboxy, alkoxy carbonyl of up to 9 carbon atoms, aralkoxy carbonyl or up to 12 carbon atoms and halogen and R' is a hydroxy protective group comprising reacting a polyphenol of the formula ##STR2## wherein R has the above definition with a base to form the corresponding dianion, reacting the latter with a trialkyl borate of the formula B(OAlk).sub.3 wherein Alk is alkyl of 1 to 6 carbon atoms to form a compound of the formula ##STR3## reacting the latter with a reagent capable of introducing a hydroxy protective group and reacting the latter with a hydrolysis agent for the oxygen-boron bond to obtain the corresponding compound of Formula I.

  将酚羟基区域特异性单官能团化到多酚上，以制备式为##STR1##的化合物，其中R选自氢、1至8个碳原子的烷基、2至8个碳原子的烯基和炔基、--CN、甲酰、羧基、最多9个碳原子的烷氧羰基、最多12个碳原子的芳基烷氧羰基和卤素的羟基保护基，包括将式为##STR2##的多酚（其中R具有上述定义）与碱反应以形成相应的二阴离子，将后者与式为B（OAlk）.sub.3的三烷基硼酸酯反应，其中Alk为1至6个碳原子的烷基，以形成式为##STR3##的化合物，将后者与能够引入羟基保护基的试剂反应，并将后者与氧硼键的水解剂反应，以获得相应的I式化合物。
• Compound for Resist and Radiation-Sensitive Composition
  申请人：Echigo Masatoshi

  公开号：US20080113294A1

  公开（公告）日：2008-05-15

  A radiation-sensitive composition containing 1 to 80% by weight of a solid component and 20 to 99% by weight of a solvent. The solid component contains a compound B which has (a) a structure derived from a polyphenol compound A by introducing an acid-dissociating group to at least one phenolic hydroxyl group of the polyphenol compound A which is synthesized by a condensation between a di- to tetrafunctional aromatic ketone or aromatic aldehyde each having 5 to 36 carbon atoms with a compound having 1 to 3 phenolic hydroxyl groups and 6 to 15 carbon atoms, and (b) a molecular weight of 400 to 2000. The composition containing the compound B is useful as an acid-amplified, non-polymeric resist material, because it is highly sensitive to radiation such as KrF excimer lasers, extreme ultraviolet rays, electron beams, and X-rays, and provides resist patterns with a high resolution, high heat resistance, and high etching resistance.

  一种辐射敏感的组合物，包含1至80重量％的固体组分和20至99重量％的溶剂。固体组分包含化合物B，其具有（a）通过向多酚化合物A的至少一个酚羟基引入酸解离基而导出的结构，多酚化合物A通过二元至四元芳香酮或芳香醛的缩合反应，每个具有5至36个碳原子的化合物与具有1至3个酚羟基和6至15个碳原子的化合物结合，并且（b）分子量为400至2000。含有化合物B的组合物非常敏感于辐射，例如KrF准分子激光器，极紫外线，电子束和X射线，并且提供具有高分辨率，高耐热性和高蚀刻抗性的抗阻图案，因此可用作酸放大的非聚合物抗阻材料。
• Method of manufacturing a semiconductor device
  申请人：Oguro Dai

  公开号：US20070059632A1

  公开（公告）日：2007-03-15

  The compound of the present invention is represented by the following formula 1: wherein R 1 , R 2 , R 4 , R 5 , m0 to m2, and n0 to n2 are as defined in the description. Radiation sensitive compositions containing the compound of the formula 1 as a main component of the solid component are excellent in sensitivity, resolution, heat resistance, etching resistance, and solubility in solvent.

  本发明的化合物由以下的公式1表示：其中，R1、R2、R4、R5、m0至m2和n0至n2的定义如描述中所述。含有公式1化合物作为固体组分主要成分的辐射敏感组合物在敏感性、分辨率、耐热性、耐蚀性和溶解度方面表现出色。
• COMPOUND FOR RESIST AND RADIATION-SENSITIVE COMPOSITION
  申请人：ECHIGO Masatoshi

  公开号：US20110165516A1

  公开（公告）日：2011-07-07

  A radiation-sensitive composition containing 1 to 80% by weight of a solid component and 20 to 99% by weight of a solvent. The solid component contains a compound B which has (a) a structure derived from a polyphenol compound A by introducing an acid-dissociating group to at least one phenolic hydroxyl group of the polyphenol compound A which is synthesized by a condensation between a di- to tetrafunctional aromatic ketone or aromatic aldehyde each having 5 to 36 carbon atoms with a compound having 1 to 3 phenolic hydroxyl groups and 6 to 15 carbon atoms, and (b) a molecular weight of 400 to 2000. The composition containing the compound B is useful as an acid-amplified, non-polymeric resist material, because it is highly sensitive to radiation such as KrF excimer lasers, extreme ultraviolet rays, electron beams, and X-rays, and provides resist patterns with a high resolution, high heat resistance, and high etching resistance.

  一种辐射敏感组合物，含有1-80重量％的固体组分和20-99重量％的溶剂。固体组分包含化合物B，其具有（a）从多酚化合物A导出的结构，通过在多酚化合物A的至少一个酚羟基上引入酸解离基团而合成，多酚化合物A是由具有5至36个碳原子的二元至四元芳香酮或芳香醛与具有1至3个酚羟基和6至15个碳原子的化合物之间的缩合反应合成的；（b）分子量为400至2000。含有化合物B的组合物可用作酸放大，非聚合物抗蚀材料，因为它对KrF准分子激光、极紫外线、电子束和X射线等辐射非常敏感，并提供具有高分辨率、高耐热性和高蚀刻抗性的抗蚀图案。
• Electrically conductive paste and coating
  申请人：Kao Corporation

  公开号：EP0467119A1

  公开（公告）日：1992-01-22

  An electrically conductive paste composition comprises an electrically conductive powder, a solvent and an organic binder comprising one or more monohydric phenol adduct compound selected from the group consisting of: (a) a monohydric phenol adduct of an unsaturated fatty acid, its metal salt or an unsaturated fatty acid ester, (b) a saturated or unsaturated fatty acid ester of said phenol adduct (a), (c) a sulfonation product of said phenol adduct (a) and (d) an amination product of said phenol adduct. It is applied to a resin article to provide an electric circuit having an improved adhesion.

  导电浆料组合物由导电粉末、溶剂和有机粘合剂组成，其中有机粘合剂包括选自以下组别的一种或多种一水苯酚加成化合物： (a) 不饱和脂肪酸、其金属盐或不饱和脂肪酸酯的一水苯酚加合物、 (b) 上述苯酚加合物(a)的饱和或不饱和脂肪酸酯、 (c) 上述苯酚加合物 (a) 的磺化产物，以及 (d) 上述苯酚加合物的胺化产物。 将其应用于树脂制品，可提供附着力更好的电路。