N,N'-di(propan-2-yl)ethane-1,2-diimine | 24764-90-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-di(propan-2-yl)ethane-1,2-diimine
• 英文别名: N,N'-diisopropyl-1,4-diaza-1,3-butadiene；N,N'-Di-isopropyl-glyoxaldiimin；Glyoxal-bis(isopropylimin)；N,N'-Bis-isopropylethylendiimin；Glyoxalbis-(isopropylimin)
• CAS: 24764-90-7
• 化学式: C₈H₁₆N₂
• 分子量: 140.228
• InChiKey: DTJSYSWZBHHPJA-NXZHAISVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.94
• 重原子数：
  10.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

安全信息

• 海关编码：
  2921199090

反应信息

• 作为反应物：
  描述：

  N,N'-di(propan-2-yl)ethane-1,2-diimine 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 反应 3.0h， 以73%的产率得到N,N'-二异丙基乙二胺
  参考文献：
  名称：

  Dieck, Heindirk tom; Verfuerth, Uwe; Diblitz, Klaus, Chemische Berichte, 1989, vol. 122, p. 129 - 132

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Propanamine, N-ethylidene-, (E)- 、 亚硝基苯 以61%的产率得到
  参考文献：
  名称：

  AURICH H. G.; HEINRICH J.-M.; WASSMUTH G., J. CHEM. RES. SYNOP., 1980, NO 7, 224, CM 3062-3077

  摘要：

  DOI：

文献信息

• Metal Complexes
  申请人：Merck Patent GmbH

  公开号：US20150171348A1

  公开（公告）日：2015-06-18

  The present invention relates to metal complexes and to electronic devices, in particular organic electroluminescent devices, comprising these metal complexes.

  这项发明涉及金属配合物以及包括这些金属配合物的电子设备，特别是有机电致发光器件。
• Compound, thin film-forming material, and thin film manufacturing method
  申请人：ADEKA CORPORATION

  公开号：US10253408B2

  公开（公告）日：2019-04-09

  A novel compound represented by the general formula (I) or (II) below: [in the formula, each of R1 and R2 independently represent a C1˜12 hydrocarbon group, and Si(R3)3 is optionally substituted for a hydrogen atom in the hydrocarbon group; however, R1 and R2 are different groups; R3 represents a methyl or ethyl group; M represents a metal atom or silicon atom; and n is an integer from 1 to 4].

  一种新型化合物，其通式为(I)或(II)如下：[在公式中，R1和R2各自独立地代表C1˜12的烃基，且Si(R3)3可选择性地替代烃基中的氢原子；然而，R1和R2是不同的基团；R3代表甲基或乙基；M代表金属原子或硅原子；n是1至4的整数]。
• [EN] ORGANOMETALLIC COMPOUNDS FOR THE MANUFACTURE OF A SEMICONDUCTOR ELEMENT OR ELECTRONIC MEMORY<br/>[FR] COMPOSÉS ORGANOMÉTALLIQUES POUR LA FABRICATION D'UN ÉLÉMENT SEMI-CONDUCTEUR OU D'UNE MÉMOIRE ÉLECTRONIQUE
  申请人：UMICORE AG & CO KG

  公开号：WO2020021083A1

  公开（公告）日：2020-01-30

  The invention relates to compounds in accordance with the general formula [Ru(arene)(Ra-N=CR1-CR3=N-Rb)] or [Ru(arene)((Rc,Rd)N-N=CRH1-CRH3=N-N(Re,Rf))]. In this case, arene is selected from the group consisting of mononuclear and polynuclear arenes and heteroarenes. R1, R3, RH1, RH3 and Ra - Rf are independently selected from the group consisting of H, an alkyl radical (C1 - C10) and an aryl radical. It further relates to methods for the production of these compounds, compounds obtainable according to these methods, their use and a substrate having on a surface thereof a ruthenium layer or a layer containing ruthenium. In addition, the invention relates to a method for producing compounds [Ru(arene)X2]2, wherein arene is selected from the group consisting of mononuclear and polynuclear arenes and X = halogen, compounds of this type obtainable according to this method, and their use. The aforementioned ruthenium(O) compounds can be produced in a simple, cost- effective and reproducible manner with a high degree of purity and good yield. Due to their high degree of purity, they are suitable for use as ruthenium(O) precursors.

  该发明涉及符合一般式[Ru(芳烃)(Ra-N=CR1-CR3=N-Rb)]或[Ru(芳烃)((Rc,Rd)N-N=CRH1-CRH3=N-N(Re,Rf))]的化合物。在这种情况下，芳烃被选自包括单核和多核芳烃以及杂环芳烃的组。R1、R3、RH1、RH3和Ra - Rf独立地选自包括H、烷基基团（C1 - C10）和芳基基团的组。它还涉及这些化合物的生产方法、根据这些方法可获得的化合物、它们的用途以及在表面上具有钌层或含钌的层的基底。此外，该发明涉及一种生产化合物[Ru(芳烃)X2]2的方法，其中芳烃被选自包括单核和多核芳烃，X = 卤素，按照该方法可获得的这类化合物及其用途。上述钌（O）化合物可以以简单、经济高效且可重复的方式生产，具有高纯度和良好的产率。由于其高纯度，它们适用于用作钌（O）前体。
• Reactions of ruthenium triphenylphosphine complexes with diazadienes. Part 1. Reactions of [RuCl2(PPh3)3] and [RuH(Cl)(PPh3)3] and disproportionation of a hydridochloro-complex
  作者：Bruno Chaudret、Rene Poilblanc

  DOI：10.1039/dt9800000539

  日期：——

  The reactions between [RuCl2(PPh3)3] and half or one equivalent of a diazadiene (dad) give respectively molecular and ionic binuclear triply chloro-bridged complexes, [Ru2Cl4(PPh3)3(dad)] and [Ru2Cl3(PPh3)2(dad)2]Cl which can also be obtained as its B Ph4 salt. The compound [RuH(Cl)(PPh3)3] reacts with diazadienes to produce [RuH(Cl)(PPh3)2(dad)], which disproportionates in polar solvents to give a

  [RuCl 2（PPh 3）3 ]与一半或一当量的二氮杂二烯（dad）之间的反应分别给出分子和离子双核三氯桥连络合物[Ru 2 Cl 4（PPh 3）3（dad）]和[Ru 2 Cl 3（PPh 3）2（dad）2 ] Cl也可以作为其B Ph 4盐获得。化合物[RuH（Cl）（PPh 3）3 ]与二氮杂二烯反应生成[RuH（Cl）（PPh 3）2（dad）]，它在极性溶剂中歧化，生成氢化物和二氯化合物，并与水反应生成氯二羟基桥接的氢化物，[Ru 2 H（µ-OH）2（PPh 3）3（爸爸）]。
• [EN] AROMATIC MONOMER-AND CONJUGATED POLYMER-METAL COMPLEXES<br/>[FR] COMPLEXES METALLIQUES A BASE DE MONOMERE AROMATIQUE ET DE POLYMERE CONJUGUE
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2005016945A1

  公开（公告）日：2005-02-24

  A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.

  描述了一种用于制备电子设备（如发光二极管(LED)设备）聚合物的卤代芳香单体-金属复合物。该芳香单体-金属复合物设计包括一个破坏共轭的连接基团，从而有利地减少或防止芳香单体片段与金属复合物片段之间的电子共轭。破坏共轭通常是为了保留从芳香单体-金属复合物形成的聚合物中金属复合物的磷光发射特性。由此产生的共轭电致发光聚合物具有精确控制的金属配合和电子性质，这些性质与聚合物主链的性质基本或完全独立。