2,4,6-tris(4-(2,2'-bipyridin-6-yl)phenyl)-1,3,5-triazine | 286459-49-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,4,6-tris(4-(2,2'-bipyridin-6-yl)phenyl)-1,3,5-triazine
• 英文别名: 2,4,6-Tris[4-(6-pyridin-2-ylpyridin-2-yl)phenyl]-1,3,5-triazine
• CAS: 286459-49-2
• 化学式: C₅₁H₃₃N₉
• 分子量: 771.883
• InChiKey: GIRCQMGZHGFTNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  60
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  116
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 2,4,6-tris(4-(2,2'-bipyridin-6-yl)phenyl)-1,3,5-triazine 以 乙二醇 为溶剂， 生成 [ruthenium(II)(2,2'-bipyridine)2(HOCH2CH2OH)]Cl2
  参考文献：
  名称：

  Metallostars containing {Ru(bpy)3} motifs

  摘要：

  Two new ligands designed to act as the core for metallostars based upon multiple bpy (bpy = 2,2'-bipyridine) metal-binding domains have been prepared. The first ligand 6 consists of a 1,3,5-triazine bearing three bpy metal-binding domains and was prepared inter alia using Stille methodology. All attempts to form complexes of 6 were unsuccessful. In contrast, a non-planar core compound based upon a tetraphenylmethane moiety bearing four bpy domains, also prepared using Stille couplings, was shown to form a tetraruthenametallostar complex containing four {Ru(bpy)(3)} motifs. Each of the {Ru(bpy)(3)} motifs is chiral, possessing Delta or Lambda chirality and detailed NMR studies indicate that the complex is formed with little or no diastereoselectivity leading to a mixture of diastereomers and a fuzzy stereochemistry. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00483-1

文献信息

• SUBSTITUTED BIPYRIDYL COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yokoyama Norimasa

  公开号：US20110001129A1

  公开（公告）日：2011-01-06

  [Problem] To provide an organic compound which shows an excellent electron-injecting/transporting performance, has a hole-blocking ability and shows a high stability as a film, that is, having excellent characteristics as a material for organic electroluminescent device having high efficiency and high durability; and to provide an organic EL device comprising the compound and having high efficiency and high durability. [Means for Solution] A substituted bipyridyl compound represented by the general formula (1); and an organic electroluminescent device comprising a pair of electrodes and at least one organic layer sandwiched between then, wherein the compound is used as the constitutive material of at least one organic layer. (wherein R 1 to R 7 may be the same or different, each representing a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a linear or branched alkyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group; n indicates an integer of from 2 to 4; A represents a di- to tetra-valent, substituted or unsubstituted aromatic hydrocarbon group, a di- to tetra-valent, substituted or unsubstituted aromatic heterocyclic group, a di- to tetra-valent, substituted or unsubstituted condensed polycyclic aromatic group, or a trivalent group represented by the following general formula (2): (wherein X, Y and Z each represents a carbon atom or a nitrogen atom); provided that when n=2, the two bipyridyl structures may direct bond to each other, and in the case, A is absent).
• TRANSPARENT ELECTRODE, ELECTRONIC DEVICE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Konica Minolta, Inc.

  公开号：US20150041789A1

  公开（公告）日：2015-02-12

  A transparent electrode includes a conductive layer and an intermediate layer disposed adjacent to the conductive layer. The intermediate layer contains a bipyridine derivative represented by the following general formula (1). The conductive layer is composed of silver as a main component. In the general formula (1), E1 to E10 each represent CR or N, and R represents a hydrogen atom or a substituent; and Ar represents a substituted or non-substituted aromatic hydrocarbon ring or a substituted or non-substituted aromatic heterocyclic ring.
• US8642189B2
  申请人：——

  公开号：US8642189B2

  公开（公告）日：2014-02-04