14,43-Bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-6,9,12,17,20,23-hexaoxa-37,40-diazaheptacyclo[26.8.4.22,5.213,16.224,27.031,39.034,38]hexatetraconta-1(37),2(46),3,5(45),13(44),14,16(43),24(42),25,27(41),28(40),29,31(39),32,34(38),35-hexadecaene | 263403-97-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 14,43-Bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-6,9,12,17,20,23-hexaoxa-37,40-diazaheptacyclo[26.8.4.22,5.213,16.224,27.031,39.034,38]hexatetraconta-1(37),2(46),3,5(45),13(44),14,16(43),24(42),25,27(41),28(40),29,31(39),32,34(38),35-hexadecaene
• 英文别名: 14,43-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-6,9,12,17,20,23-hexaoxa-37,40-diazaheptacyclo[26.8.4.22,5.213,16.224,27.031,39.034,38]hexatetraconta-1(37),2(46),3,5(45),13(44),14,16(43),24(42),25,27(41),28(40),29,31(39),32,34(38),35-hexadecaene
• CAS: 263403-97-0
• 化学式: C₅₀H₄₂N₂O₁₀S₂
• 分子量: 895.023
• InChiKey: OYUUMPIBIQXRPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  64
• 可旋转键数：
  2
• 环数：
  14.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  175
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  zinc perchlorate 、 5,5'-bis([2,2'-bithiophen]-5-yl)-2,2'-bipyridine 、 14,43-Bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-6,9,12,17,20,23-hexaoxa-37,40-diazaheptacyclo[26.8.4.22,5.213,16.224,27.031,39.034,38]hexatetraconta-1(37),2(46),3,5(45),13(44),14,16(43),24(42),25,27(41),28(40),29,31(39),32,34(38),35-hexadecaene 以 二氯甲烷 、 乙腈 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Three-Strand Conducting Ladder Polymers: Two-Step Electropolymerization of Metallorotaxanes

  摘要：

  Sequential polymerization of supramolecular metallorotaxane complexes results in three-stranded conducting ladder polymers. The internal polymer is "sandwiched" between the other two polymers to give molecular wires that are effectively insulated when the outer polymers are in their nonconducting state (shown schematically). The intermolecular conductivity can be mediated by the Cu(1+)/Cu(2+) redox couple.

  DOI：

  10.1002/(sici)1521-3773(20000204)39:3<608::aid-anie608>3.0.co;2-w
• 作为产物：
  描述：

  2,9-bis(4-hydroxyphenyl)-1,10-phenanthroline 在 bis-triphenylphosphine-palladium(II) chloride copper(l) iodide 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 14,43-Bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-6,9,12,17,20,23-hexaoxa-37,40-diazaheptacyclo[26.8.4.22,5.213,16.224,27.031,39.034,38]hexatetraconta-1(37),2(46),3,5(45),13(44),14,16(43),24(42),25,27(41),28(40),29,31(39),32,34(38),35-hexadecaene
  参考文献：
  名称：

  Three-Strand Conducting Ladder Polymers: Two-Step Electropolymerization of Metallorotaxanes

  摘要：

  Sequential polymerization of supramolecular metallorotaxane complexes results in three-stranded conducting ladder polymers. The internal polymer is "sandwiched" between the other two polymers to give molecular wires that are effectively insulated when the outer polymers are in their nonconducting state (shown schematically). The intermolecular conductivity can be mediated by the Cu(1+)/Cu(2+) redox couple.

  DOI：

  10.1002/(sici)1521-3773(20000204)39:3<608::aid-anie608>3.0.co;2-w

文献信息

• Three-Strand Conducting Ladder Polymers: Two-Step Electropolymerization of Metallorotaxanes
  作者：Julio Buey、Timothy M. Swager

  DOI：10.1002/(sici)1521-3773(20000204)39:3<608::aid-anie608>3.0.co;2-w

  日期：2000.2.4

  Sequential polymerization of supramolecular metallorotaxane complexes results in three-stranded conducting ladder polymers. The internal polymer is "sandwiched" between the other two polymers to give molecular wires that are effectively insulated when the outer polymers are in their nonconducting state (shown schematically). The intermolecular conductivity can be mediated by the Cu(1+)/Cu(2+) redox couple.